Several studies have reported on the detection of perchlorate (ClO(4)(-)) in edible leafy vegetables irrigated with Colorado River water. However, there is no information on spinach as related to ClO(4)(-) in irrigation water nor on the effect of other anions on ClO(4)(-) uptake. A greenhouse ClO(4)(-) uptake experiment using spinach was conducted to investigate the impact of presence of chloride (Cl(-)) and nitrate (NO(3)(-)) on ClO(4)(-) uptake under controlled conditions. We examined three concentrations of ClO(4)(-), 40, 220, and 400 nmol(c)/L (nanomoles of charge per liter of solution), three concentrations of Cl(-), 2.5, 13.75, and 25 mmol(c)/L, and NO(3)(-) at 2, 11, and 20 mmol(c)/L. The results revealed that ClO(4)(-) was taken up the most when NO(3)(-) and Cl(-) were lowest in concentration in irrigation water. More ClO(4)(-) was detected in spinach leaves than that in the root tissue. Relative to lettuces, spinach accumulated more ClO(4)(-) in the plant tissue. Perchlorate was accumulated in spinach leaves more than reported for outer leaves of lettuce at 40 nmol(c)/L of ClO(4)(-) in irrigation water. The results also provided evidence that spinach selectively took up ClO(4)(-) relative to Cl(-). We developed a predictive model to describe the ClO(4)(-) concentration in spinach as related to the Cl(-), NO(3)(-), and ClO(4)(-) concentration in irrigation water.
High-resolution evapotranspiration (ET) maps can assist demand-based irrigation management. Development of high-resolution daily ET maps requires high-resolution land surface temperature (LST) images. Earth-observing satellite sensors such as the Landsat 5 Thematic Mapper (TM) and MODerate resolution Imaging Spectroradiometer (MODIS) provide thermal images that are coarser than simultaneously acquired visible and near-infrared images. In this study, we evaluated the TsHARP downscaling technique for its capability to downscale coarser LST images using finer resolution normalized difference vegetation index (NDVI) data. The TsHARP technique was implemented to downscale seven coarser scale (240, 360, 480, 600, 720, 840, and 960 m) synthetic images to a 120 m LST image. The TsHARP was also evaluated for downscaling a coarser 960 m LST image to 240 m to mimic MODIS datasets. Comparison between observed 120 m LST images and 120 m LST images downscaled from coarser 240, 360, 480, 600, 720, 840, and 960 m images yielded root mean square errors of 1.0, 1.3, 1.5, 1.6, 1.7, 1.8, and 1.9°C, respectively. This indicates that the TsHARP method can be used for downscaling coarser (960 m) MODIS-based LST images using finer Landsat (120 m) or MODIS (240 m)-derived NDVI images. However, the TsSHARP method should be evaluated further with real datasets before using it for an operational ET remote sensing program for irrigation scheduling purposes.
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