Here we report the designing of chiral metamaterial with metallic helix array. The effective electric and magnetic dipoles, which originate from the induced surface electric current upon illumination of incident light, are collinear at the resonant frequency. Consequently, for the circularly polarized incident light, negative refractive index is realized. Our design provides a unique approach to tune the optical properties by assembling helices, and demonstrates a different approach in exploring threedimensional chiral metamaterial.
Fourier transform infrared ͑FTIR͒ spectrometer is a powerful tool for studying the photoluminescence ͑PL͒ properties of semiconductors, due to its well-known multiplexing and throughput advantages. However, it suffers from internal He-Ne laser disturbance in near-infrared and/or environmental background thermal emission in mid-and far-infrared spectral regions. In this work, a modulated PL technique is developed based on step-scan ͑SS͒-FTIR spectrometer. Theoretical analysis is conducted, and applications of the technique are given as examples in the PL study of mid-infrared HgCdTe thin films and near-infrared GaInP / AlGaInP multiple quantum wells, respectively. The results indicate that the He-Ne laser and/or thermal emission disturbance can be reduced at least 1 / 1000 and/or even 1 / 10 000, respectively, by the modulated SS-FTIR PL technique, and hence a rather smooth PL spectrum can be obtained even under room temperature for HgCdTe thin films. A brief comparison is given of this technique with previously reported phase-sensitive modulation methods based on conventional rapid-scan ͑RS͒-FTIR spectrometer, and the advantages of this technique over the former RS-FTIR-based ones are emphasized.
Pure Ca(5)(PO(4))(2)SiO(4) bioceramic was first prepared by a sol-gel method using triethyl phosphate, tetraethoxysilane, and calcium nitrate tetrahydrate as original materials. Simulated body fluid (SBF) immersion tests revealed that Ca(5)(PO(4))(2)SiO(4) samples had a greater in vitro apatite-forming ability than hydroxyapatite (HA). After soaking Ca(5)(PO(4))(2)SiO(4) samples in the SBF for 1 day, bone-like apatite precipitated on the surfaces and the apatite layer became thicker with increasing the soaking time. However, few bone-like apatites precipitated on the HA samples even after soaking in the SBF for 7 days. The good in vitro bioactivity of Ca(5)(PO(4))(2)SiO(4) samples was attributed to the silanol (Si-OH) groups and greater solubility of Ca(5)(PO(4))(2)SiO(4). In addition, hot-pressed Ca(5)(PO(4))(2)SiO(4) ceramic exhibited lower bending strength and elastic modulus than hot-pressed HA, since the former had a lower relative density than the latter. The results have shown that Ca(5)(PO(4))(2)SiO(4) is a potential candidate material for bone repair.
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