Magnetic impurities are crucial for probing spin-polarized topological surface states. Scanning tunneling microscopy (STM) studies of Fe on the Bi 2 Te 3 (111) surface are preformed and unveil distinct impurity structures of unknown origin which exhibit temperature-dependent characteristics. Using density functional theory with spin-orbit coupling, we show that Fe prefers highly coordinated subsurface configurations. By comparing simulated STM images we can explain the experimental results of both low-temperature deposition, in which Fe exists in metastable states of which only the transition metal-Bi split interstitial is STM visible, and after room-temperature annealing, in which iron forms substitutional Fe Bi .
We have a continuing interest in applying the current knowledge of cytochrome P450cam substrate recognition to engineer the enzyme for the biotransformation of unnatural substrates with the long-term aim of applications in the synthesis of fine chemicals and bioremediation of environmental contaminants. Comparisons of the structure of target substrates with that of camphor, the natural substrate, led to the design of active-site mutants with greatly enhanced activity for the oxidation of chlorinated benzenes and selectivity of (+)-alpha-pinene oxidation. The crystal structures of the F87W/Y96F/V247L mutant with 1,3,5-trichlorobenzene or (+)-alpha-pinene bound have revealed the enzyme-substrate contacts and provided insights into the activity and selectivity patterns. The structures have also provided a novel basis for further engineering of P450cam for increased activity in the oxidation of the highly inert pentachlorobenzene and hexachlorobenzene, and increased selectivity of (+)-alpha-pinene oxidation.
Proposed is a novel ergodic capacity formula for decode-and-forward (DF) relaying over a very general fast fading channel model, i.e. the channel gains of the links follow independent but non-necessarily identically distributed Nakagami-m distributions. The proposed formula is validated by Monte Carlo simulations and can be computed efficiently. Since the considered channel model is very general, the proposed formula is appropriate for evaluating the performance of DF relaying in a wide variety of realistic wireless channel environments.
The SCOR-model contains five primary man agement processes, namely, Plan, Source, Make, Deliver, and Return. The development of radio frequency identifica tion (RFID) technology provides an efficient way to improve the supply chain performance. In this paper, the application of RFID technology in a SCOR-model driven enterprise production system (EPS) is introduced. The framework and architecture of the RFID-based EPS are proposed to inte grate the RFID devices into the production system. After wards the main processes of the SCOR-model driven EPS are illustrated, problems concerning communication be tween the RFID devices and the EPS are discussed as well.With the application of RFID, the improvement of SCOR performance metrics is analyzed in the end.
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