Antibacterial
air filtration membranes are essential for personal
protection during the pandemic of coronavirus disease 2019 (COVID-19).
However, high-efficiency filtration with low pressure drop and effective
antibiosis is difficult to achieve. To solve this problem, an innovative
electrospinning system with low binding energy and high conductivity
was built to enhance the jet splitting, and a fluffy nanofibrous membrane
containing numerous ultrafine nanofibers and large quantities of antibacterial
agents was achieved, which was fabricated by electrospinning polyamide
6 (PA6), poly(vinyl pyrrolidone) (PVP), chitosan (CS), and curcumin
(Cur). The filtration efficiency for 0.3 μm NaCl particles was
99.83%, the pressure drop was 54 Pa, and the quality factor (QF) was
up to 0.118 Pa–1. CS and Cur synergistically enhanced
the antibacterial performance; the bacteriostatic rates against Escherichia coli and Staphylococcus
aureus were 99.5 and 98.9%, respectively. This work
will largely promote the application of natural antibacterial agents
in the development of high-efficiency, low-resistance air filters
for personal protection by manufacturing ultrafine nanofibers with
enhanced antibiosis.
Mass loading of functional particles on the surface of nanofibers is the key to efficient heavy metal treatment. However, it is still difficult to prepare nanofibers with a large number of functional particle loads on the surface simply and efficiently, which hinders the further improvement of performance and increases the cost. Here, a new one-step strategy was developed to maximize the adhesion of graphene oxide (GO) particle to the surface of polyvinylidene fluoride (PVDF) nanofibers, which was combined with coaxial surface modification technology and blended electrospinning. The oxygen content on the as-prepared fiber surface increased from 0.44% to 9.32%, showing the maximized GO load. The increased adsorption sites and improved hydrophilicity greatly promoted the adsorption effect of Cr(VI). The adsorption capacity for Cr(VI) was 271 mg/g, and 99% removal rate could be achieved within 2 h for 20 mL Cr(VI) (100 mg/L), which was highly efficient. After five adsorption–desorption tests, the adsorption removal efficiency of the Cr(VI) maintained more than 80%, exhibiting excellent recycling performance. This simple method achieved maximum loading of functional particles on the fiber surface, realizing the efficient adsorption of heavy metal ions, which may promote the development of heavy-metal-polluted water treatment.
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