The understanding of the migration of mercury from packaging materials to food stuffs is the prerequisite for the development of food safety regulations. In this article, the migration of mercury from food paper-plastic packaging containers to four food stimulants under different migrated temperatures is studied. The results show that the mobility and the maximum migration volume of mercury increase at certain temperatures when the migration time is extended. It is also noted that the time to reach equilibrium is reduced as the temperature increases. Meanwhile, different solvents appear various different while the rates of migration are 3% acetic acid >10% ethanol >20% ethanol >50% ethanol. But they show the same trend at the different temperatures. Our data suggest that different solvents, temperatures, and food stimulants affect the migration rates, and ameliorate those conditions will reduce migration and promote food quality.
We demonstrate that Mn-doping in the layered sulfides Bi4O4S3 leads to stable Bi4−xMnxO4S3 compounds that exhibit both long-range ferromagnetism and enhanced superconductivity for 0.075 ≤ x ≤ 0.15, with a possible record superconducting transition temperature (Tc) ∼ 15 K amongst all BiS2-based superconductors. We conjecture that the coexistence of superconductivity and ferromagnetism may be attributed to Mn-doping in the spacer Bi2O2 layers away from the superconducting BiS2 layers, whereas the enhancement of Tc may be due to excess electron transfer to BiS2 from the Mn 4+ /Mn 3+ -substitutions in Bi2O2. This notion is empirically corroborated by the increased electron-carrier densities upon Mn doping, and by further studies of the Bi4−xAxO4S3 compounds (A = Co, Ni; x = 0.1, 0.125), where the Tc values remain comparable to that of the undoped Bi4O4S3 system (∼ 4.5 K) due to lack of 4+ valences in either Co or Ni ions for excess electron transfer to the BiS2 layers. These findings therefore shed new light on feasible pathways to enhance the Tc values of BiS2-based superconductors, although complete elucidation of the interplay between superconductivity and ferromagnetism in these anisotropic layered compounds awaits the development of single crystalline materials for further investigation. a
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