Since colossal ionic conductivity was detected in the planar heterostructures consisting of fluorite and perovskite, heterostructures have drawn great research interest as potential electrolytes for solid oxide fuel cells (SOFCs). However, so far, the practical uses of such promising material have failed to materialize in SOFCs due to the short circuit risk caused by SrTiO3. In this study, a series of fluorite/perovskite heterostructures made of Sm-doped CeO2 and SrTiO3 (SDC–STO) are developed in a new bulk-heterostructure form and evaluated as electrolytes. The prepared cells exhibit a peak power density of 892 mW cm−2 along with open circuit voltage of 1.1 V at 550 °C for the optimal composition of 4SDC–6STO. Further electrical studies reveal a high ionic conductivity of 0.05–0.14 S cm−1 at 450–550 °C, which shows remarkable enhancement compared to that of simplex SDC. Via AC impedance analysis, it has been shown that the small grain-boundary and electrode polarization resistances play the major roles in resulting in the superior performance. Furthermore, a Schottky junction effect is proposed by considering the work functions and electronic affinities to interpret the avoidance of short circuit in the SDC–STO cell. Our findings thus indicate a new insight to design electrolytes for low-temperature SOFCs.

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Bacterial cellulose (BC) is an environmentally friendly biomaterial that is widely investigated because it possesses a unique hierarchical nanofiber network structure as well as extraordinary performance. In this review, the formation of the BC hierarchical nanofiber network structure from the perspective of biosynthesis is illustrated based on its basic chemical and crystal structure. Moreover, the design and processing of BC-based advanced materials through biosynthesis, physical, and/or chemical modification are also reviewed. The intrinsic characteristics of BC, derived from its hierarchical structure, are analyzed to understand its structure-property-application relationships. The applications of advanced BC-based materials are reviewed, such as high-strength structural materials utilizing the properties of nanofibers, energy conversion and storage, bioelectronic interfaces, environmental remediation, and thermal management applications utilizing the ion transport properties and 3D network structures of these materials. In addition, the authors also offer their opinions and potential future research directions for sustainably developing BC-based materials.

The emerging water purification technology represented by solar water evaporation has developed rapidly in recent years and is widely used in seawater desalination. However, the high reflectivity of sunlight and low efficiency of photothermal conversion greatly hinder its application prospects. In this paper, the hierarchical structure of the film was designed and optimized by the addition of carbon materials in the process of bacterial cellulose culture. A cellulose-based composite film material with a microporous structure was obtained, which can improve the photothermal evaporation rate and photothermal conversion efficiency from the structural principle to improve the stability of floating on the water. Bacterial cellulose (BC) as a threedimensional carrier was combined with one-dimensional and two-dimensional (1D/2D) compounds of carbon nanotubes (CNT) and reduced graphene oxide (RGO) to form composite films for solar evaporation. By the addition of CNT−RGO (21.8 wt %), the composite showed prominent photothermal evaporation rate and photothermal conversion efficiency properties. Through in situ culture of BC, not only a tight structure can be obtained but also the surface of BC contains a large number of hydroxyl groups, which have many active sites to load photothermal materials. BC nanofibers, CNT, and RGO cooperate to form a porous network structure, which provides continuous double channels for the rapid transmission of water molecules and light paths, so as to form an excellent photothermal layer. The photothermal conversion efficiency is 90.2%, and the photothermal evaporation rate is 1.85 kg m −2 h −1 to achieve efficient solar interface evaporation. This is a high level of photothermal properties in a cellulose-based solar steam generator. The superior photothermal performance of this hybrid film possesses scalability and desalination ability.

With the booming development of flexible wearable sensing devices, flexible stretchable strain sensors with crack structure and high sensitivity have been widely concerned. However, the narrow sensing range has been hindering the development of crack-based strain sensors. In addition, the existence of the crack structure may reduce the interface compatibility between the elastic matrix and the sensing material. Herein, to overcome these problems, integrated core-sheath fibers were prepared by coaxial wet spinning with partially added carbon nanotube sensing materials in thermoplastic polyurethane elastic materials. Due to the superior interface compatibility and the change in the conductive path during stretching, the fiber strain sensor exhibits excellent durability (5000 tensile cycles), high sensitivity (>10 4 ), large stretchability (500%), a low detection limit (0.01%), and a fast response time of ∼60 ms. Based on these outstanding strain sensing performances, the fiber sensor is demonstrated to detect subtle strain changes (e.g., pulse wave and swallowing) and large strain changes (e.g., finger joint and wrist movement) in real time. Moreover, the fabric sensor woven with the core-sheath fibers has an excellent performance in wrist bending angle detection, and the smart gloves based on the fabric sensors also show exceptional recognition ability as a wireless sign language translation device. This integrated strategy may provide prospective opportunities to develop highly sensitive strain sensors with durable deformation and a wide detection range.