The manuscript presents an outstanding synergistic effect of aluminum diethylphosphinate (AlPi) and epoxy-functional polysiloxane (EPM) for preparing flame-retardant poly(butylene terephthalate) (PBT).

We successfully prepared a highly effective flame-retardant additive called hsalbenzoguanamine phosphaphenanthrene (HDPD) through salicylaldehyde and nitrogen-rich benzoguanamine. The introduction of HDPD into epoxy resin (EP) sharply enhanced the flame retardancy of EP/HDPD thermosets. The introduction of 6 wt% HDPD into EP succeeded in reaching the V-0 rating. Limited oxygen index results revealed the high flame-retarding performance of HDPD. Cone calorimeter test data revealed that heat and smoke released from EP/6 wt% HDPD thermoset were significantly restrained. In addition, EP/6 wt% HDPD thermoset demonstrated excellent transmittance and mechanical strength. The transmittance of EP/6 wt% HDPD was assessed from 520 to 800 nm. The results showed that transmittance of EP/6 wt% HDPD were nearly 90% of the control group.

An epoxy-functional polysiloxane (EPM) was employed for improving the performance of flame-retarded poly(butylene terephthalate)/aluminum diethylphosphinate (PBT/AlPi) composites. The effect was investigated by UL-94 test, limiting oxygen index, mechanical test, torque rheometer measurement, differential scanning calorimetry, dynamic mechanical analysis, and heat distortion temperature. An obvious increase in torque evolution of the PBT/AlPi composite during processing was associated with chain-extending, branching, and cross-linking reaction by the combination of EPM. The addition of 0.6 wt% EPM remarkably enhanced not only the mechanical properties but also the flame retardancy and heat resistance of the PBT/AlPi composite. A high-performance PBT/AlPi composite was developed by virtue of EPM.

Calcium carbonate is so hard to be further developed in polymer applications because it is difficult to combine with other materials. Starch-coated calcium carbonate was prepared by using starch as the main modifier and sodium stearate and sodium hexametaphosphate as the auxiliary modifiers. Optimal modification conditions were tested by single factor experiment and orthogonal experiment optimization. Manifestation was evaluated with the help of Fourier infrared spectrometer (FT-IR) and laser particle size analyzer and other test instruments. Results showed that a starch film was successfully coated on the surface of calcium carbonate, and the edges and corners of the modified coated calcium carbonate were passivated, and the particles were rounded. The active interface calcium carbonate has a broad application prospect in the field of degradable biomaterials.