Seed vitality is one of the primary determinants of high yield that directly affects the performance of seedling emergence and plant growth. However, seed vitality may be lost during storage because of unfavorable conditions, such as high moisture content and temperatures. It is therefore vital for seed companies as well as farmers to test and determine seed vitality to avoid losses of any kind before sowing. In this study, near-infrared hyperspectral imaging (NIR-HSI) combined with multiple data preprocessing methods and classification models was applied to identify the vitality of rice seeds. A total of 2400 seeds of three different years: 2015, 2016 and 2017, were evaluated. The experimental results show that the NIR-HSI technique has great potential for identifying vitality and vigor of rice seeds. When detecting the seed vitality of the three different years, the extreme learning machine model with Savitzky–Golay preprocessing could achieve a high classification accuracy of 93.67% by spectral data from only eight wavebands (992, 1012, 1119, 1167, 1305, 1402, 1629 and 1649 nm), which could be developed for a fast and cost-effective seed-sorting system for industrial online application. When identifying non-viable seeds from viable seeds of different years, the least squares support vector machine model coupled with raw data and selected wavelengths of 968, 988, 1204, 1301, 1409, 1463, 1629, 1646 and 1659 nm achieved better classification performance (94.38% accuracy), and could be adopted as an optimal combination to identify non-viable seeds from viable seeds.
Sugarcane tops were extracted with 50% ethanol and fractionated by petroleum ether, ethyl acetate (EtOAc), and n-butyl alcohol successively. Eight phenolic compounds in EtOAc extracts were purified through silica gel and Sephadex LH-20 column chromatographies, and then identified by nuclear magnetic resonance and electrospray ionization mass spectra. The results showed that eight phenolic compounds from EtOAc extracts were identified as caffeic acid, cis-p-hydroxycinnamic acid, quercetin, apigenin, albanin A, australone A, moracin M, and 5'-geranyl-5,7,2',4'-tetrahydroxyflavone. The antioxidant and nitrite-scavenging capacities of different solvent extracts correlated positively with their total phenolic (TP) contents. Amongst various extracts, EtOAc extracts possessed the highest TP content and presented the strongest oxygen radical absorbance capacity (ORAC), 1,1'-diphenyl-2-picrylhydrazyl (DPPH) radical-scavenging capacity, 2,2'-azobis-3-ethylbenthiaazoline-6-sulfonic acid (ABTS) radical-scavenging capacity, ferric reducing antioxidant power (FRAP) and nitrite-scavenging capacity. Thus, sugarcane tops could be promoted as a source of natural antioxidant.
The Mogou syenite intruded into the Mesoproterozoic Xiong'er Group is the main lithostratigraphic unit, along the southern margin of the North China Craton (NCC). This paper reports zircon LA-ICP-MS data, whole-rock major and trace element compositions of late Triassic magmatic rocks in the Mogou syenite, in order to constrain the formation age of the Mogou syenite, research the origin and evolution of the magma and analyse the geodynamic setting of the Qinling Orogen (QO) in Late Triassic. These rocks consist of medium-to coarse-grained syenite and fine-grained quartz syenite. Zircon U-Pb dating yields a crystallization age of 226.5±2.7 Ma. The syenites are characterized by high SiO 2 (63.49-72.17%), alkali (K 2 O+Na 2 O of 11.18-15.38%) and potassium (K 2 O/Na 2 O of 2.88-28.11), are peralkaline or metaluminous (molar A/CNK of 0.87-1.02) and belong to shoshonite series. The syenites have ΣREE of 33.01-191.30 ppm, LREE/HREE of 14-20, (La/Yb) N of 11-24, with LREE-rich distribution pattern and obvious differentiation between HREE and LREE. Eu anomalies are positive for the medium-to coarse-grained syenite and weakly negative for the fine-grained quartz syenite. In addition, the syenites are enriched in large-ion lithophile elements (Ba, K, Sr, and Pb) but depleted in high strength field elements (Ti, Ta, Nb, Zr, and Hf), and have high differentiation indices of 91.69-97.06. These geochemical features indicate that the primary magma of the Mogou syenite most likely originated from a mantle source with minor crustal component, and underwent a fractional crystallization process during its emplacement. The late Triassic A-type Moguo syenite along the southern margin of the NCC was generated in the late stage of the syn-collision event of QO, recording a transition period from compression to extension at around 227 Ma.
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