Corresponding authors: Chongmin.wang@pnnl.gov, xsun9@uwo.ca, Jiguang.zhang@pnnl.gov # These authors contribute equally to this work. ABSTRACT:The biggest challenge for the commercialization of layered structured nickel rich lithium transition metal oxide cathode is the capacity and voltage fading. Resolving this problem over the years follows an incremental progress. In this work, we report our finding of totally a new approach to revolutionize the cycle stability of aggregated cathode particles for lithium ion battery at both room and elevated temperatures. We discover that infusion of a solid electrolyte into the grain boundaries of the cathode secondary particles can dramatically enhance the capacity retention and voltage stability of the battery. We find that the solid electrolyte infused in the boundaries not only acts as a fast channel for Li ion transport, but also most importantly prevents penetration of the liquid electrolyte into the boundaries, consequently eliminating the detrimental factors that include solid-liquid interfacial reaction, intergranular cracking, and layer to spinel phase transformation. The present work, for the first time, reveals unprecedented insight as how the cathode behaves in the case of not contacting with the liquid electrolyte, ultimately points toward a general new route, via grain boundary engineering, for designing of better batteries of both solid-liquid and solid state systems.

Single atom catalyst, which contains isolated metal atoms singly dispersed on supports, has great potential for achieving high activity and selectivity in hetero-catalysis and electrocatalysis. However, the activity and stability of single atoms and their interaction with support still remains a mystery. Here we show a stable single atomic ruthenium catalyst anchoring on the surface of cobalt iron layered double hydroxides, which possesses a strong electronic coupling between ruthenium and layered double hydroxides. With 0.45 wt.% ruthenium loading, the catalyst exhibits outstanding activity with overpotential 198 mV at the current density of 10 mA cm −2 and a small Tafel slope of 39 mV dec −1 for oxygen evolution reaction. By using operando X-ray absorption spectroscopy, it is disclosed that the isolated single atom ruthenium was kept under the oxidation states of 4+ even at high overpotential due to synergetic electron coupling, which endow exceptional electrocatalytic activity and stability simultaneously.

We present the first Event Horizon Telescope (EHT) observations of Sagittarius A* (Sgr A*), the Galactic center source associated with a supermassive black hole. These observations were conducted in 2017 using a global interferometric array of eight telescopes operating at a wavelength of λ = 1.3 mm. The EHT data resolve a compact emission region with intrahour variability. A variety of imaging and modeling analyses all support an image that is dominated by a bright, thick ring with a diameter of 51.8 ± 2.3 μas (68% credible interval). The ring has modest azimuthal brightness asymmetry and a comparatively dim interior. Using a large suite of numerical simulations, we demonstrate that the EHT images of Sgr A* are consistent with the expected appearance of a Kerr black hole with mass ∼4 × 106 M ⊙, which is inferred to exist at this location based on previous infrared observations of individual stellar orbits, as well as maser proper-motion studies. Our model comparisons disfavor scenarios where the black hole is viewed at high inclination (i > 50°), as well as nonspinning black holes and those with retrograde accretion disks. Our results provide direct evidence for the presence of a supermassive black hole at the center of the Milky Way, and for the first time we connect the predictions from dynamical measurements of stellar orbits on scales of 103–105 gravitational radii to event-horizon-scale images and variability. Furthermore, a comparison with the EHT results for the supermassive black hole M87* shows consistency with the predictions of general relativity spanning over three orders of magnitude in central mass.

Recently a population of compact radio galaxies were classified as Fanaroff-Riley type 0 radio galaxies (FR 0s). The physical nature of FR 0s and the connection with the classical FR I and II galaxies are not currently well understood. Here, we report the radio properties of fourteen FR 0s on parsec (pc) scales derived from their very long baseline interferometry (VLBI) imaging observations. All sources show compact structures. Four sources show relativistic beaming with Doppler boosting factors ranging from 1.7 to 6. The brightness temperatures of the other ten are below the equilibrium limit. Jet proper motions are determined in two sources which have multiple epoch data, between 0.23 c and 0.49 c, implying mildly relativistic jet flow. Low-amplitude flux density variation is found in J0943+3614 over a time period of 10 years. No significant variability are detected in three other sources over time scales of a few years. The radio properties of the FR 0s inferred from the VLBI data resemble GHz-peaked spectrum or compact steep-spectrum sources. Moreover, the diversity of their relativistic beaming indicators (brightness temperature, variability, jet proper motion) also imply that FR 0s might not be a homogeneous population of radio sources. Detailed studies of the low-power (P 1.4GHz < 10 24 W Hz −1 ) FR 0 sources in the local Universe additionally offer a promising opportunity to understand their connection to the FR Is.