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Original graphene oxide (GO) nanosheets were prepared using the Hummers method and found to easily aggregate in aqueous and cement composites. Using carboxymethyl chitosan (CCS) as a dispersant, few-layered GO nanosheets (1–2 layers) were obtained by forming CCS/GO intercalation composites. The testing results indicated that the few-layered GO nanosheets could uniformly spread, both in aqueous and cement composites. The cement composites were prepared with GO dosages of 0.03%, 0.05% and 0.07% and we found that they had a compact microstructure in the whole volume. A special feature was determined, namely that the microstructures consisted of regular-shaped crystals created by self-crosslinking. The X-ray diffraction (XRD) results indicated that there was a higher number of cement hydration crystals in GO/cement composites. Meanwhile, we also found that partially-amorphous Calcium-Silicate-Hydrate (C-S-H) gel turned into monoclinic crystals. At 28 days, the GO/cement composites reached the maximum compressive and flexural strengths at a 0.05% dosage. These strengths were 176.64 and 31.67 MPa and, compared with control samples, their increased ratios were 64.87% and 149.73%, respectively. Durability parameters, such as penetration, freeze-thaw, carbonation, drying-shrinkage value and pore structure, showed marked improvement. The results indicated that it is possible to obtain cement composites with a compact microstructure and with high performances by introducing CCS/GO intercalation composites.

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Abstract:In this work, we found that by controlling the size of the graphene oxide nanosheets (GON) at 5-140 nm, 5-260 nm and 5-410 nm, respectively, we could prepare regular shaped cement hydration crystals with the shape of nano-needle-like, flower-like, and polyhedron-like crystals, respectively. Together, these crystals formed an ordered structure of cement composites on both the micro and macro levels, and the compressive and flexural strengths of the cement composites obviously increased when compared to the control samples. Our results indicated that the smallest structural unit of regular crystals was the nano-polyhedron-like crystals, which consisted of AFt, AFm, CH, and crystallization C-S-H, and could assemble into regular needle-like crystals, flower-like crystals, and polyhedron-like crystals, as well as an ordered structure on the micro and macro levels. Most of the C-S-H was transferred into a monoclinic system crystals and the remainder played the role of an adhesive in the forming process of regular crystals and structure. The cracks and holes in the cement composites disappeared by the self-repairing effect of the growing hydration crystal. The results indicate that ordered structural cement composites with defect-free structures and high strength can be prepared using GON with a suitable size range.

The present work determined the influence of superhydrophobic nano-SiO2 on the hydraulic conductivity and pore size distribution of expansive soil, and analysed the mechanism of modification between superhydrophobic nano-SiO2 and expansive soil from a microscopic view. Superhydrophobic nano-SiO2 was added to expansive soil as a modifier. Our samples were of two types, i.e., unmodified (without nano-SiO2) and modified (with 0.2%, 0.4%, 0.6%, 0.8%, and 1.0% nano-SiO2 by weight of the parent soil). The hydraulic conductivity decreased with increasing nano-SiO2 content. Fourier transform mid-infrared test revealed that some silanols in soil and nano-SiO2 were dehydrated and condensed to form siloxanes. We inferred that nano-SiO2 can attach onto the surface of soil particles to form a hydrophobic membrane, which reduced the soil expansion and the change in pore size distribution. And microscopic tests showed that the pore volume and hydrophilicity of the soil samples decreased with increasing SiO2 content. According to the Young–Laplace equation, the minimum permeable pore radius was calculated in the hydraulic-conductivity test. With increasing nano-SiO2 content, the volume of permeable pore decreased. It had an excellent linear relationship with the hydraulic conductivity and permeable pore volume of samples containing different nano-SiO2 contents. Therefore, superhydrophobic nano-SiO2 could effectively reduce hydraulic conductivity by changing the pore size distribution of expansive soil.