Logic gate functions built with nonvolatile resistive
switching
and thermoresponsive memory based on biologic proteins were investigated.
The “NAND” and “NOR” functions of logic
gates in soya protein devices have been built at room temperature
by their nonvolatile ternary WORM resistive switching behaviors. Furthermore,
heating the devices from room temperature to 358 K results in a switch
from tristable state to bistable state WORM resistive switching behavior,
indicating that the thermoresponsiveness can be efficiently memorized.
The biologic transient nonvolatile memory device consisting of soya
protein is illustrated. This device exhibits a long data retention
time (104 s) and significant HRS/LRS ratio (∼105); the transient response of the current to voltage of an
as-fabricated device is also explored. The soya protein based memory
device on a gelatin film substrate is also assessed to validate the
feasibility of degradation and biological compatibility for the implantable
biological electronic device, that is, innoxious and avirulent to
the human body. This can offer alternative avenues for exploring prospective
bioelectronic devices.
The shuttle effect of soluble lithium polysulfides (LiPSs) between electrodes and slow reaction kinetics lead to extreme inefficiency and poor high current cycling stability, which limits the commercial application of Li–S batteries. Herein, the multi-dimensional composite frame has been proposed as the modified separator (MCCoS/PP) of Li–S battery, which is composed of CoS2 nanoparticles on alkali-treated MXene nanosheets and carbon nanotubes. Both experiments and theoretical calculations show that bifunctional catalytic activity can be achieved on the MCCoS/PP separator. It can not only promote the liquid–solid conversion in the reduction process, but also accelerate the decomposition of insoluble Li2S in the oxidation process. In addition, LiPSs shuttle effect has been inhibited without a decrease in lithium-ion transference numbers. Simultaneously, the MCCoS/PP separator with good LiPSs adsorption capability arouses redistribution and fixing of active substances, which is also beneficial to the rate performance and cycling stability. The Li–S batteries with the MCCoS/PP separator have a specific capacity of 368.6 mAh g−1 at 20C, and the capacity decay per cycle is only 0.033% in 1000 cycles at 7C. Also, high area capacity (6.34 mAh cm−2) with a high sulfur loading (7.7 mg cm−2) and a low electrolyte/sulfur ratio (7.5 μL mg−1) is achieved.
Decorating Ru does not effect the morphology of NWs, increased the oxygen vacancies, adsorbed oxygen. This strategy results in a better sensing performance (∼120 to 100 ppm ethanol was increased around 47 times at 200 °C) and humidity resistance.
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