Photocatalytic H2 evolution (PHE) from extremely abundant seawater resources is an ideal way to secure sustainable H2 for humanity, but the saline in seawater easily competitively absorbs the active sites and poisons the catalyst. Herein, a series of low-cost alkali halide (NaI, KI, RbI, CsI, CsBr, and CsCl), analogous to the saline in natural seawater, was selected to modify carbon nitride (MX-CN) through one-step facile pyrolysis with the assistance of water. MX-CN possesses a large amount of negative charges, which could inhibit anion absorption, to some extent, preventing chloride corrosion. Importantly, it can greatly boost the electron transfer between MX-CN and triethanolamine (TEOA) (sacrificial agent) because the alkali cation in seawater can coordinate with TEOA, and easily come in contact with MX-CN through alkali-cation exchange and electrostatic attraction. Benefiting from it, the PHE performance in seawater is 200 times better than that of original CN in deionized water above, and the apparent quantum efficiency of MX-CN (CsI-CN) under 420 nm light irradiation comes to 72% in seawater, the highest value reported for seawater thus far. This work provides a new research direction for engineering the electron transfer pathway between the photocatalyst and sacrificial agent (e.g., pollutant) in natural seawater.

No abstract

Ventilation and heating can be necessary for pig production during winter in China. However, it is challenging to balance the ventilation rate and heat loss due to the ventilation. Therefore, it is essential to design the minimum ventilation and heating load properly in order to reduce energy loss. In this paper, a VBA (Visual Basic for Applications) model based on energy balance is established. Meteorological data, pig body masses, outdoor temperatures, feeding densities, and building envelope thermal insulance factors were involved in the model. A model pig house with a length and width of 110 m × 15 m was used to investigate the ventilation, heating time, load, and power consumption in different climate zones, i.e., Changchun, Beijing, Nanning, Wuhan, and Guiyang, representing five major climate regions in China. Based on the simulation results, the models of minimum ventilation and heating load were fitted. The results showed that there is a logarithmic relationship between the minimum ventilation volume and body mass, R2 = 0.9673. The R2 of heating load models for nursery pigs and fattening pigs were 0.966 and 0.963, respectively, considering the feeding area, the outside temperature, the body masses of the nursery and fattening pigs, and the thermal insulance factor of the enclosure. The heating requirements of commercial pig houses within the same building envelope followed the trend in Changchun > Beijing > Guiyang > Wuhan > Nanning. Increasing the building envelope’s thermal insulance factor or using precision heating could reduce the pig house’s power consumption. The analysis of the heating load and energy consumption of winter pig houses in various climate regions provided a reference for precise environmental control and the selection of building thermal insulance factors in China.