We report B/N co-doped carbon materials synthesized by a carbonization method with ferric catalyst treatment from a precursor with boric acid treatment after the formation of the composite between waterborne polyurethane and graphene oxide.
Temperature-resolved weight loss and tar yield during atmospheric devolatilization of pulverized coal have been obtained on a wire mesh reactor (WMR), which imposes prescribed thermal histories covering a wide range of heating rates on coals from lignite to anthracite. The accuracy of measurements has been improved by diminishing non-isothermality in the sample, ensuring independence of yields on loading density, and the development of a convenient tar collection method that inhibits secondary pyrolysis but also secures capture completeness. We reconfirm the continuous rank effects in terms of reaction dynamics and partitioning between tar and non-condensables but at disparate heating rates of 5 and 1000 K/s. In addition, we depict the constant variation in gas evolution histories among various coals before the cessation of tar release, whereas since the end of tar evolution, variations in gas formation kinetics for different coals gradually shrink with increasing temperatures. A larger fraction of total gases is found expelled after tar evolution by coals of higher rank. The sensitivity of the tar yield to heating rate is maintained the same over the range of 5−1000 K/s but varies with rank, being greatest for lignites and low-volatile bituminous coals but exhibiting a minimum for high-volatile bituminous coals.
Not only dose oral administration have the highest safety, convenience and patient compliance, but also can improve patients' quality of life and reduce health care costs in many cases when compared to the parenteral route. However, many drugs, especially most anticancer drugs such
as paclitaxel (PTX), are not orally bioavailable, which is attributed to low aqueous solubility, poor intestinal permeability, and the high level of P-glycoprotein (P-gp) efflux. In this study, we developed a nano-porous silica aerogel delivery system for oral administration of PTX that improved
the bioavailability, reduced the side effects of the drug and inhibited tumor growth. The advantages of nano-porous silica aerogel include very high porosities, vast specific surface areas, high drug-loading rate, high biological safety, excellent biocompatibility, and biological inertia,
which can also be applied to a variety of drugs. The aerogel delivery system is a universal pharmaceutical system that has huge potential in the field of pharmacy.
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