In order to avoid the appearance of soft particles composed of ferrite or pearlite in the actual production of new bainitic steel, the phase transformation behaviour and bainite formation kinetics were investigated by DIL805A dilatometer, optical microscopy, scanning electron microscopy and Vickers-durometer. The results show that the soft particles cannot appear when the cooling rate exceeds 0.025 K s −1 , and this condition can be ensured by direct spray cooling in production. The local activation energy decreases with increasing transformed bainite volume fraction ( f b ), and the average energy is about 136.7 kJ mol −1 . The local Avrami exponent mainly lies between 0.5 and 3 in a wide f b range, indicating that the dominating mechanism of bainite formation is two-dimensional and one-dimensional growth.
The corrosion behavior of cemented carbides with binders of different chemical nature (Co and Ni) and carbides with distinct mean grain size (ultrafine and coarse) was studied. The investigation also included corrosion media (acidic and neutral solutions containing chlorides and an alkaline solution) as experimental variables. Immersion tests were performed to induce corrosion damage in a controlled way. Electrochemical parameters were measured together with a detailed inspection of the corroded surfaces. Microstructural influence on the tolerance to corrosion damage was evaluated in terms of residual strength. Results pointed out that corrosion rates were lower in the alkaline solution. In contrast, acidic media led to higher corrosion rates, especially for cemented carbides with Co regardless the influence of carbide mean grain size. Corrosion damage resulted in strength degradation due to the formation of surface corrosion pits in acidic solution. In neutral and alkaline solutions, much less pronounced effects were determined. Focused Ion Beam (FIB)/ Field Emission Scanning Electron Microscopy (FESEM) results revealed differences in corrosion-induced damage scenario. In acidic solution, corrosion starts at binder pool centers and evolves towards binder/WC interfaces. Meanwhile, corrosion in alkaline solution is initially located at binder/WC interfaces, and subsequently expands into the ceramic particles, developing a microcrack network inside this phase.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.