We report a comprehensive study of the tridimensional nature and orbital characters of the low-energy electronic structure in KCo2Se2, using polarization- and photon energy-dependent angle-resolved photoemission spectroscopy. We observed one electron-like Fermi surface (FS) at the Brillouin zone (BZ) center, four electron-like FSs centered at the BZ corner, and one hole-like FS at the BZ boundary. The FSs show weak dispersion along the kz direction, indicating the near-two-dimensional nature of FSs in KCo2Se2. In combination with the local-density approximation calculations, we determined the orbital characters of the low-energy electronic bands, which are mainly derived from the Co 3d orbital, mixed with part of the Se 4p states. The [Formula: see text] orbital gives a significant contribution to the band crossing the Fermi level. A band renormalization of about 1.6 is needed to capture the essential dispersive features, which suggests that electronic correlations are much weaker than that in KyFe2-xSe2.

Using the angle-resolved photoemission spectroscopy and band structure calculations we study the electronic structure of KFeCoAs, which is isoelectronic to the parent material of 122 series of iron-based superconductors BaFeAs. Although band structure calculations predict nearly identical dispersions of the electronic states in both compounds, experiment reveals drastic differences in both the global renormalization and Fermi surfaces. On the basis of the comparison of electronic structures of these two isoelectronic compounds, we demonstrate local magnetic correlations as a vital role for the peculiar low-energy electron dynamics of iron-based superconductors.