A stable and reproducible superconductivity transition between 80 and 93 K has been unambiguously observed both resistively and magnetically in a new Y-Ba-Cu-0 compound system at ambient pressure. An estimated upper critical field H, 2(0) between 80 and 180 T was obtained.
We have found a remarkable increase (up to 60%) of the dielectric constant with the onset of magnetic order at 42 K in the metastable orthorhombic structures of YMnO 3 and HoMnO 3 that proves the existence of a strong magnetodielectric coupling in the compounds. Magnetic, dielectric, and thermodynamic properties show distinct anomalies at the onset of the incommensurate magnetic order and thermal hysteresis effects are observed around the lock-in transition temperature at which the incommensurate magnetic order locks into a temperature independent wave vector. The Mn 3+ spins and Ho 3+ moments both contribute to the magnetodielectric coupling. A large magnetodielectric effect was observed in HoMnO 3 at low temperature where the dielectric constant can be tuned by an external magnetic field resulting in a decrease of up to 8% at 7 T. By comparing data for YMnO 3 and HoMnO 3 the contributions to the coupling between the dielectric response and Mn and Ho magnetic moments are separated. The coupling between dielectric and magnetic properties recently observed in some manganites [1][2][3][4][5][6] and in other oxides 7,8 is of fundamental interest and of eminent significance for potential applications. The anomalies of dielectric (magnetic) properties at magnetic (ferroelectric) phase transitions and the possibility of tuning the dielectric constant (magnetization) by external magnetic (electric) fields open alternate perspectives in the basic understanding of the interesting materials and for the design of devices. The magnetodielectric effect can be explained by a spin-lattice coupling due to an increase of magnetic exchange energy when the magnetic ions shift their positions. 9,10 This effect is particularly strong close to or below a magnetic phase transition and may result in structural anomalies and a change of the dielectric properties.The rare earth manganites, RMnO 3 (R = rare earth metal), exhibit strong magnetic exchange interactions between the magnetic moments of the Mn 3+ ions as well as some of the magnetic R 3+ . Depending on the rare earth ionic size, RMnO 3 crystallizes in either hexagonal or orthorhombic (distorted perovskite) structure with the structural phase boundary between Ho and Dy. However, some of the hexagonal compounds can also be synthesized as a metastable phase in the orthorhombic structure by either special chemical procedures 11 or high pressure synthesis. 12 The hexagonal phases of RMnO 3 show ferroelectricity below Curie temperatures between 590 and 1000 K and antiferromagnetic (AFM) transitions below 100 K with small but distinct anomalies in the dielectric constant at or below the magnetic transitions.1-4 Since symmetry arguments do not allow a direct coupling between the Mn magnetic order and the polarization in the hexagonal structure the observed magnetodielectric coupling has to be related to secondary interactions but a microscopic explanation of these effects is not yet available. Some work has been done to investigate possible magnetodielectric effects in the orthorhombic...
1ft 'J .Ó AP E418 Superconductivity ExperimentS uperconductivity may beome one of the most signifcant inovations of mom times. Ths is a result of very recent discoveries of high temperature superconductorswhich may revolutionize everything from electrcal generation and transmission to high-speed cQmputers to controlled fusion generatig plants.In ths experiment, you will investigate the superconductivity of the new Y -Ba-Cu-O compound system as a function of temperature and magnetic field. The most important question should should answer is "What is the resistance of the superconductor as the temperatu and applied magnetic field ar changed?" Other questions which you wil not be able to answer are related to the determination of curent density which can pass through the material and the mechanical strength and elasticity of the material.Attached to these notes are some articles which describe aspects of superconductivity and the results of recent measurements of the Y -Ba-Cu-O compound made by Prof. M. K. Wu and co-workers. These wil provide background for the experiments that you wil be penormg. Pay paricular attention to Prof. Wu's aricle. Their measurements are identical to those that you can obtan with the equipment supplied in the laboratory. Next, look over the description of tye 1 and j , ty.e 2 superconductors given by Gennes in Superconductivity in Metals and Alloys.o.f\1. , l' -Type 1 superconductors have a "correlation length" between. conduction electrons ((sheri (denoted by the symbol, ÇO) much longer than the magnetic field penetration length ( denoted by Â.). They generally have a very abrupt crtical field, He, below which the P-i1lèt material is superconducting and excludes all magnetic flux. (H e is a function of temperature.) This "penect diamagnetîsm" is charaèteristic of the superconducting state. Type 2 superconductors have Â. ~ Ço and have a more gradual transition to this superconducting state. They are described by thee critical magnetic fields. Below Hci (the lowest critical field), a typ 2 superconductor has no resistace and, like a type 1 superconductor, excludes flux. Between H c1 and H e2, the resistance is very low, but finite, and the superconductor parally excludes flux. Between He2 and He3, the resistance is low, but no flux is excluded. Finally, above the highest of the three crtical fields, He3. the material is no longer superconducting. DescrI ptionThe Y -Ba-Cu-O compound becomes superconducting between 77 and 85 eK.This makes the cryogenic aspects of these experiment very easy compared with experiments using more conventional superconductors that require temperatures below 22 eK. Liquid nitrogen is relatively inexpensive and a styrofoam thermos is al that is required to store it for several hours.-We have built three LN2 containers for you, and these are large enough to hold stainless-steel and copper "sample stands". The sample stands cool the 1 \, W£t.~ i-superconducting sample and provide a stable base to make your measurements. Also, attached to each sample is a calibrated t...
We have found superconductivity in the 90-K range in ^Ba2Cu306+x with A = La, Nd, Sm, Eu, Gd, Ho, Er, and Lu in addition to Y. The results suggest that the unique square-planar Cu atoms, each surrounded by four or six oxygen atoms, are crucial to the superconductivity of oxides in general. In particular, the high T c of /!Ba2Cu3C>6+x is attributed mainly to the quasi two-dimensional assembly of the Cu02-Ba-CuC>2+x-Ba-Cu02 layers sandwiched between two A layers, with particular emphasis in the Cu02+* layers. Higher-T c oxides are predicted for compounds with bigger assemblies of Cu02 layers coupled by Ba layers.
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