The aryl to vinyl palladium 1,4-migration was realized for the first time. The generated alkenyl palladium species was trapped by diboron reagents under Miyaura borylation conditions, providing a new method to synthesize β,β-disubstituted vinylboronates. The excellent regioselectivity and broad substrate scope were observed for this novel transformation.

A synthetic aperture radar (SAR) target recognition approach is developed in this paper by exploiting the multiscale monogenic components, which are extracted from SAR images based on the 2D monogenic signal. The 2D canonical correlation analysis is then employed to analyze the correlations of the same monogenic components at different scales. Afterwards, the three monogenic components, i.e., local amplitude, local phase, and local orientation, at different scales are fused as three feature matrices, respectively. In order to further capture the correlations between different types of monogenic components, the joint sparse representation is used for target classification. Therefore, both the correlations of the same monogenic components at multiple scales and the relatedness among different types of monogenic components can be exploited in the proposed scheme. The real measured SAR images from the moving and stationary target acquisition and recognition dataset are classified to examine the validity of the proposal. Compared with some state-of-the-art SAR target recognition methods, the proposed approach is validated to be superior under both standard operating condition and several usual extended operating conditions according to the experimental results. In comparison with some other methods, which also use monogenic components as the basic features, the superiority of the proposed method demonstrates that it could better make use of the monogenic components to improve the classification performance. INDEX TERMS Synthetic aperture radar (SAR), target recognition, monogenic signal, 2D canonical correlation analysis (2DCCA), joint sparse representation (JSR).

The enantioselective rhodium-catalyzed 1,2-addition of arylboronates to cyclic N-sulfamidate alkylketimines was developed. With a rhodium/diene complex as catalyst, high enantioselectivity and broad functional group tolerance were observed. The resulting sulfamidates can easily be converted into chiral β-alkyl-β-aryl amino alcohols.