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SnO2/BiOBr photocatalyst with broad‐spectrum response was one step constructed via in situ hydrothermal method; SnO2 was anchored on the surface of BiOBr sheets by acidolysis of Na2SnO3 in the stock solution producing BiOBr. The photocatalytic degradation activity over rhodamine B (RhB) under visible light‐emitting diode irradiation of BiOBr is further improved by coupling a 7% amount of SnO2. The reaction rate constant of 7%SnO2/BiOBr is 8.2 times that of pristine BiOBr. The enhanced photocatalytic performance can be ascribed to the excellent adsorption abilities for RhB, broadening visible light response, and efficient transfer of photogenerated electrons from BiOBr to SnO2.

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A 2D/2D BiPO4/g-C3N4-B nano-sheet heterojunction photocatalyst was synthesized via a simple coprecipitation method at room temperature using glacial acetic acid as solvent, which showed excellent activity toward the degradation of rhodamine B (RhB). The heterojunction showed much higher efficiency of separation and transfer of photogenerated carriers compared to that of its constituents. Moreover, the spectral response range of BiPO4 was effectively broadened after the combination of g-C3N4-B and BiPO4. Consequently, a 97.3% degradation of RhB within 25 min by BiPO4/g-C3N4-B heterojunction photocatalyst under visible light irradiation was observed. The difference in work functions of BiPO4 and g-C3N4-B was evident from UPS characterization, which led to the bending of the energy band and the establishment of an internal electric field at the interface of the heterojunction. Therefore, the synthesized direct Z-type BiPO4/g-C3N4-B heterojunction enhanced the oxidation-reduction ability by promoting the effective separation of photogenerated carriers.