Electromagnetic absorbers have drawn increasing attention in many areas. A series of plasmonic and metamaterial structures can work as efficient narrowband absorbers due to the excitation of plasmonic or photonic resonances, providing a great potential for applications in designing selective thermal emitters, biosensing, etc. In other applications such as solar-energy harvesting and photonic detection, the bandwidth of light absorbers is required to be quite broad. Under such a background, a variety of mechanisms of broadband/multiband absorption have been proposed, such as mixing multiple resonances together, exciting phase resonances, slowing down light by anisotropic metamaterials, employing high loss materials and so on.
Plasmonic photoelectrochemical (PEC) water splitting is very promising in the conversion of abundant solar energy into chemical energy. However, the solar-to-hydrogen efficiencies reported so far are still too low for practical use, which can be improved by optimizing the design and synthesis of individual blocks (i. e., the compositions, sizes, shapes of the metal and the coupling semiconductors) and the assembly of these blocks into targeted three-dimensional (3D) structures. Here, we constructed a composite plasmonic metal/semiconductor photoanode by decorating gold nanoparticles (Au NPs) on 3D branched ZnO nanowire arrays (B-ZnO NWs) through a series of simple solution chemical routes. The 3D ordered Au/B-ZnO NWs photoanodes exhibited excellent PEC activities in both ultraviolet and visible region. The improved photoactivities in visible region were demonstrated to be caused by the surface-plasmon-resonance effect of Au NPs. The photoconversion efficiency of Au/B-ZnO NWs photoanode reached 0.52% under simulated sunlight illumination. This is a high value of solar-to-hydrogen efficiencies reported till nowadays for plasmonic PEC water splitting, which was mainly benefit from the extensive metal/semiconductor interfaces for efficient extraction of hot electron from Au NPs and excellent charge-carries collection efficiency of the 3D ordered Au/B-ZnO NWs photoelectrode.
Optical resonators with high quality factors (Qs) are promising for a variety of applications due to the enhanced nonlinearity and increased photonic density of states at resonances. In particular, frequency combs (FCs) can be generated through four-wave mixing in high-Q microresonators made from Kerr nonlinear materials such as silica, silicon nitride, magnesium fluoride, and calcium fluoride. These devices have potential for on-chip frequency metrology and high-resolution spectroscopy, high-bandwidth radiofrequency information processing, and high-data-rate telecommunications. Silicon nitride microresonators are attractive due to their compatibility with integrated circuit manufacturing; they can be cladded with silica for long-term stable yet tunable operation, and allow multiple resonators to be coupled together to achieve novel functionalities. Despite previous demonstrations of high-Q silicon nitride resonators, FC generation using silicon nitride microresonator chips still requires pump power significantly higher than those in whispering gallery mode resonators made from silica, magnesium, and calcium fluorides, which all have shown resonator Qs between 0.1 and 100 billion. Here, we report on a fabrication procedure that leads to the demonstration of "finger-shaped" Si 3 N 4 microresonators with intrinsic Qs up to 17 million at a free spectrum range (FSR) of 24.7 GHz that are suitable for telecommunication and microwave photonics applications. The frequency comb onset power can be as low as 2.36 mW and broad, single FSR combs can be generated at a low pump power of 24 mW, both within reach of on-chip semiconductor lasers. Our demonstration is an important step toward a fully integrated on-chip FC source. Kerr comb generation in microresonators starts when an external continuous-wave (CW) laser is tuned into a cavity resonance; this causes intracavity power to build, which enables additional cavity modes to oscillate through nonlinear wave mixing [10]. FC formation has now been demonstrated in a variety of Kerr nonlinear materials such as silica [9,14-18], silicon nitride (Si 3 N 4 ) [19-21], aluminum nitride [22], CaF 2 [23], and MgF 2 [24]. Recently, dissipative Kerr solitons have also been demonstrated in MgF 2 and Si 3 N 4 optical microresonators [25,26]. Out of these materials, stoichiometric Si 3 N 4 has distinctive 2334-2536/16/111171-10 Journal
Although perovskite light-emitting diodes (PeLEDs) have recently experienced significant progress, there are only scattered reports of PeLEDs with both high efficiency and long operational stability, calling for additional strategies to address this challenge. Here, we develop perovskite-molecule composite thin films for efficient and stable PeLEDs. The perovskite-molecule composite thin films consist of in-situ formed high-quality perovskite nanocrystals embedded in the electron-transport molecular matrix, which controls nucleation process of perovskites, leading to PeLEDs with a peak external quantum efficiency of 17.3% and half-lifetime of approximately 100 h. In addition, we find that the device degradation mechanism at high driving voltages is different from that at low driving voltages. This work provides an effective strategy and deep understanding for achieving efficient and stable PeLEDs from both material and device perspectives.
There has been great interest in the silicon platform as a material system for integrated photonics. A key challenge is the development of a low-power, low drive voltage, broadband modulator. Drive voltages at or below 1 Vpp are desirable for compatibility with CMOS processes. Here we demonstrate a CMOS-compatible broadband traveling-wave modulator based on a reverse-biased pn junction. We demonstrate operation with a drive voltage of 0.63 Vpp at 20 Gb/s, a significant improvement in the state of the art, with an RF energy consumption of only 200 fJ/bit.
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