To mitigate the dust dispersion pollution in the open-pit coal mines, this study experimentally develops a novel environmentally friendly coal dust suppressant. The experiment uses naturally biodegradable soybean protein isolate (SPI) as the main material and utilizes anion surfactant sodium dodecyl sulfate (SDS) to modify SPI. In the carboxymethylcellulose sodium and sodium silicate and other auxiliary agents, this process produces gives rise to the SDS-SPI coal dust suppressant. Experimental characterization of the developed dust suppressant reveals that the viscosity of the 5% dust suppressant solution can reach 24.6 mPa s. Correspondingly, the compressive strength reaches 0.48 MPa, and the dust suppression efficiency can reach 93.47% with the presence of force 9 wind. Furthermore, this study uses Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) to analyze the dust suppression mechanism of the developed dust suppressant. It is observed that a layer of compact hardened shell is formed at the surface of the coal powder treated with the newly developed dust suppressant. Also, there exists a strong cementing effect among dust particles, yielding a decent cementing performance. Therefore, the present dust suppressant can effectively suppress dust dispersion in the open-pit coal mines, allowing a mitigation of the environmental pollution.
In an effort to effectively control coal dust pollution and thereby reduce the harm of coal dust to human health, we prepared a highly efficient composite dust suppressant. First, dynamic contact angle and zeta potential measurements were used to select sodium dodecyl sulfonate (SDS) over sodium carboxymethyl cellulose and trisodium methyl silicon as the complementary additive to soy protein isolate for the dust suppressant. We employed viscosity and wind erosion resistance tests to compare the performance of the composite dust suppressant with three common, commercially available suppressants. As the concentration of the composite dust suppressant was increased, the viscosity increased, reaching a maximum value of 22.7 mPa·s at a concentration of 5 wt%. The 5 wt% concentration of the composite dust suppressant provided the lowest wind erosion rate (20.62%) at a wind speed of 12 m/s. The composite dust suppressant also had good bonding performance and wind erosion resistance. Scanning electron microscopy, X-ray diffraction, and thermogravimetric analysis were used to characterize the properties of the dust suppressants. The dust suppressant, which had a crystal-like structure, could easily capture coal dust and form an effective package. In addition, the density of the dust suppressant film increased as its crystallinity increased. The increased density was beneficial in that it enabled the dust suppressant to form a hard, solidified shell on the surface of coal dust, which improved dust suppression. The composite dust suppressant also had good thermal stability.
In an effort to control dust pollution in open-air environments such as pit coal mines and coal transportation systems, a new dust suppressant with a cross-linked network structure was prepared. Graft copolymerization of soy protein isolate (SPI) and methacrylic acid (MAA), using potassium persulfate (KPS) as the initiator and hexametaphosphoric acid (SHMP) as the cross-linking agent, formed the network structure. The optimal MAA/SPI mass ratio for the dust suppressant was determined through a single factor experiment to be 3:4, with 0.8 and 0.2 g of SHMP and KPS, respectively. The grafting reaction required 30 min at 60 ℃. Scanning electron microscopy, energy-dispersive x-ray spectroscopy, Fourier-transform infrared spectroscopy, and differential scanning calorimetry were used to characterize the structure and application performance of the dust suppressant. The experimental results showed that the graft copolymerization reaction successfully formed the desired cross-linked network, and that when the cross-linked network material was sprayed on coal dust it formed a dense, solidi ed shell, which effectively resisted wind erosion and served as a dust suppressant. The average reduction of the total suspended particulate matter of an open-air coal pile reached 79.95%, demonstrating effective dust suppression.
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