No abstract

No abstract

The design of new polymeric materials and the search for new classes of polymers for industrial application in membrane-based gas separation have been the focus of several research groups worldwide. Membranes with high productivity and efficiency under harsh operational conditions of pressure and temperature during mixed-gas separation are of great interest. In this paper, we report the preparation of a series of block copolymers of poly(imide−oxadiazole)s built from 6FDA, Durene, and four different 1,3,4-oxadiazole-based monomers. The pureand mixed-gas separation properties of their corresponding membranes were measured. The mixed-gas separation data were collected at a high feed pressure of up to 900 psi. Such mixed-gas separation testing under harsh conditions is required to subject the membranes to environments similar to industrial use. For example, the mixed-gas CO 2 permeability of 6FDA-Durene/6FDA-4BAO(Me) (3:1) was measured at 900 psi to be ∼130 barrer, and the CO 2 /CH 4 selectivity is around ∼24. These results of permeability and selectivity of poly(imide−oxadiazole) membranes at such high gas feed pressure are considered very attractive and are superior to many glassy polymers reported in the literature and that are industrially observed membranes. This work illustrates well a case scenario of structure−property relationship and demonstrates the exclusivity of mixed-gas testing which could not be predicted from the ideal situation of pure-gas testing. In the near future, the mixed-gas separation properties of thin layer composite and hollow fibers will be evaluated.

The current process to purify contaminated natural gas reserves employs a highly energy-intensive amine scrubbing technology. To satisfy the growing demand for natural gas coupled with the tight regulations on CO 2 emissions, researchers worldwide are investigating the use of polymeric membranes for acid gas removal from natural gas streams, to reduce the energy consumption and carbon emission of the nowadays used technology. Placing a polymeric membrane unit at the upstream of the amine scrubbing column reduces the energy consumption during the regeneration process of saturated amines. Hence, the preparation of polymeric membranes in form of hollow fibers is a key step towards their industrial implementation for natural gas processing.The following study demonstrates the potential separation performance of 6FDA-Durene/6FDA-CARDO (5000:5000) in an integrally skinned defect-free asymmetric hollow fiber geometry. The initial screening studies of the membrane shows good pure-gas performance as it exhibits CO 2 /CH 4 selectivity coefficients around 28 and CO 2 permeance between 310 and 350 GPU. Feed pressures of up to 900 psig and stage cuts ranging from 5% to 20% were tested for a quaternary sweet mixed-gas feed to assess the membrane performance under operating conditions that mimic those in industrial settings. Mixed-gas permeance of all gases, and CO 2 /CH 4 selectivity remain somewhat constant as the feed pressure increases up to 900 psig. Both mixed-gas CO 2 permeance and CO 2 /CH 4 selectivity decline as the stage cut increases. As expected, as CO 2 recovery is maximized, CO 2 purity is minimized and CH 4 loss increases with increasing stage cut. As a result of the trade-off between recovery and purity, the data and analyses reported herein can provide insights into the limitations that certain operating parameters can pose on CO 2 separation performance with similar polymeric hollow fiber membranes.