An atomically thin optoelectronic memory array for image sensing is demonstrated with layered CuIn7Se11 and extended to InSe and MoS2 atomic layers. Photogenerated charge carriers are trapped and subsequently retrieved from the potential well formed by gating a 2D material with Schottky barriers. The atomically thin layered optoelectronic memory can accumulate photon-generated charges during light exposure, and the charges can be read out later for data processing and permanent storage. An array of atomically thin image memory pixels was built to illustrate the potential of fabricating large-scale 2D material-based image sensors for image capture and storage.
Uranium capture from
seawater could solve increasing energy demand
and enable a much needed relaxing from fossil fuels. Low concentration
(∼3 ppb), competing cations (especially vanadium) and pH-dependent
speciation prohibit highly efficient uranium uptake. Despite intensive
research, selective extraction of uranyl ions over vanadyl units remains
a tremendous challenge. Here, we adopted a molecular coordination
template strategy to design a uranyl-specific bis-salicylaldoxime
entity and decorated it into a highly porous aromatic framework (PAF-1)
by programmable assembly. The superstructure (MISS-PAF-1) gives a
strong affinity that removes 99.97% of uranium in 120 min. Notably,
it binds to the uranyl ion at least 100 times more selectively than
14 different cations tested, including the vanadyl ion, in simulated
seawater at ambient pH. Real seawater samples collected from the Bohai
Sea achieve 5.79 mg g
–1
of uranium capacity over
56 days without PAF degradation, exceeding a 4-fold higher amount
than commercial adsorbents.
We develop fully glycosylated computational models of ACE2-Fc fusion proteins which are promising targets for a COVID-19 therapeutic. These models are tested in their interaction with a fragment of the receptor-binding domain (RBD) of the Spike Protein S of the SARS-CoV-2 virus, via atomistic molecular dynamics simulations. We see that some ACE2 glycans interact with the S fragments, and glycans are influencing the conformation of the ACE2 receptor. Additionally, we optimize algorithms for protein glycosylation modelling in order to expedite future model development. All models and algorithms are openly available.
2D materials have been widely studied over the past decade for their potential applications in electronics and optoelectronics. In these materials, elemental composition plays a critical role in defining their physical properties. Here we report the first successful synthesis of individual high quality CuIn 7 Se 11 (CIS) ternary 2D layers and demonstrate their potential use in photodetection applications. Photoconductivity measurements show an indirect bandgap of 1.1 eV for few-layered CIS, an external quantum efficiency of 88.0 % with 2 V bias across 2 µm channel with and a signal-to-noise ratio larger than 95 dB. By judicious choice of electrode materials, we demonstrate the possibility of layered CIS-based 2 2D photovoltaic devices. This study examines this ternary 2D layered system for the first time, demonstrating the clear potential for layered CIS in 2D material-based optoelectronic device applications.
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