The composition of Bayan Obo iron ore concentrate is complex. If a large proportion is used to prepare pellets, abnormal swelling will occur during blast furnace smelting. This paper studies the swelling behavior of pellets prepared from Bayan Obo iron ore concentrate in stages during the reduction process; XRD and SEM-EDS analysis and calculates the crystal parameters of the reduction products in each stage. The results show that the total RSI of pellets prepared from Bayan Obo iron ore concentrate is as high as 35%, and the third stage of reduction has the maximum swelling rate, which is 24%. The mechanisms of the three stages reduction swelling of pellets are the crystal transformation, the effect of slag phase and the growth of iron whiskers. The results can enrich the reduction swelling theory of pellets prepared from complex intergrowth minerals.
To explore the reduction
swelling process of pellets prepared from
the Bayan Obo iron ore concentrate, based on the iron oxide reduction
theory of pellets, the reduction of pellets prepared from the Bayan
Obo iron ore concentrate was analyzed by thermogravimetric experiments
and kinetic calculations in three stages. The reason for the abnormal
swelling of pellets prepared from the Bayan Obo iron ore concentrate
was analyzed from the perspective of kinetics. The research results
showed that carbon deposition occurred in the first stage of reduction.
The second stage of reduction was controlled by an interfacial chemical
reaction, and the activation energy of the reaction was 117.99 kJ/mol.
The reaction energy barrier was higher and the reaction rate was slower,
and therefore, the reduction swelling rate of pellets was lower at
this stage. The third stage of reduction was controlled by internal
diffusion, and the reaction activation energy was 15.9 kJ/mol. The
reduction reaction of pellets occurs violently, and the reduction
swelling behavior was remarkable at this stage.
The process of crack propagation and tunnel failure is affected by the cross-sectional geometry of an underground tunnel. In order to quantify the effect of section shape on the process of crack propagation in deep tunnels under high ground stress conditions, a total of four physical models with two cross-sectional shapes and twelve stress levels were designed and several large-scale physical model tests were conducted. The results indicated that, when the vertical stress is 4.94 MPa, the length and depth of the cracks generated in the rock surrounding the horseshoe tunnel are about eight times that around a circular tunnel. The position where the circumferential displacement of the horseshoe tunnel begins to be stable is about two, to two and a half, times that around a circular tunnel. After the deep chamber was excavated, continuous spalling was found to occur at the foot of the horseshoe tunnel and microcracks in the surrounding rock were initially generated from the foot of the side wall and then developed upwards to form a conjugate sliding shape to the foot of the arch roof, where the cracks finally coalesced. Discontinuous spalling occurred at the midheight of the side wall of the circular tunnel after excavation, and microcracks in the surrounding rock were initially generated from the midheight of the side wall and then extended concentrically to greater depth in the rock mass surrounding the tunnel. Tensile failure mainly occurred on the surface of the side wall: shear failure mainly appeared in the surrounding rock.
Low-ash-melting-point
bituminous coal and high-ash-melting-point
anthracite coal are mixed and burned in different proportions. The
ash melting characteristics of blended coal were determined experimentally.
At the same time, the ash samples of bituminous coal, anthracite,
and blended coal were analyzed by X-ray diffraction (XRD), and the
ash melting characteristic improvement mechanism of blended coal was
analyzed by quantum chemical calculations. The results show that when
high-ash-melting-point anthracite is added, the ash melting characteristics
of blended coal are improved, and the deformation temperature, softening
temperature, hemispheric temperature, and flow temperature of the
blended coal are significantly increased. The melting point of blended
coal ash with a bituminous coal ratio of less than 50% can meet the
requirements of blast furnace injection. The reason for the improved
melting characteristics of the blended coal ash is that mullite in
anthracite ash reacts with gehlenite in bituminous coal ash during
the combustion process to produce anorthite.
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