Experimental studies were conducted to enhance the oil recovery by a surfactant-polymer binary combinational flooding system. The surfactant-polymer binary combinational flooding was obtained by mixing the surfactants with the poly(AM-NVP-AS)-1 which was an anti-temperature and salt-resistance tercopolymer and successfully synthesized via free radical polymerization using acrylamide (AM), N-vinyl pyrrolidone (NVP), allyl sulfonate (AS) as raw materials. The initiator was redox system including watersoluble azo compound (AIBAÁ2HCl) and sodium bisulfite (NaHSO 3 ). Petroleum carboxylate dodecyl dibasic carbonylic acid sodium (C12DAS) and carboxyl betaine dodecyl dimethyl betaine (C12DB) were selected in this article. Compared with the surfactant-HPAM, the surfactant-poly(AM-NVP-AS)-1 binary combinational system showed higher apparent viscosity and lower interfacial tension at high temperature and salinity conditions as the result of a better capacity of anti-temperature, salt-resistance, and swept volume. The recovery could enhance over 17% based on the core flooding test under the mineralization of 10,000 mg=L at 65 C.
To alleviate the uneven production
of extreme heterogeneous reservoirs,
we developed a high-strength natural gas foamed gel system by adding
a gel system to the foaming agent solution. The Ostwald ripening rate
and the gas molecular diffusion coefficient (D
diff) were calculated. The number of bubbles, the average diameter(D
ad), and the poly-dispersion coefficient (U
poly) of the foamed gel system have been considered
within, as well as the different temperature, salinity, pressure,
and crude oil conditions and the stability of the foamed gel system.
Moreover, combining laboratory displacement experiments and core nuclear
magnetic (NMR) experiments, the oil displacement ability of natural
gas foamed gel was studied. The results showed that different from
the previous phenomenon of “defoaming with oil”, adding
a certain amount of crude oil into the natural gas foamed gel could
improve its foaming performance. According to this phenomenon, we
conducted experiments on the stability and viscosity enhancement of
the emulsion and explored the stability of the pseudo-emulsion film
of foamed gel. In addition, this natural gas foamed gel system had
a better ability to control profile and enhance oil recovery when
the permeability ratio was 75–150. When the permeability ratio
was 150, the low-permeability core diversion rate was about 38%, and
the EOR was 35.27%. Finally, the core NMR results showed that the
main contribution of water flooding recovery came from macropores.
In construct, the recovery efficiency of natural gas foamed gel system
mainly came from medium and small pores (effective areas not affected
by water flooding). This study would provide a different thought for
foam in production while dealing with extreme heterogeneity formations.
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