The removal of organic dyes and pathogenic bacteria from
contaminated
water remains a significant challenge. In the present study, S-type
heterojunction Ag2MoO4/ZnFe2O4 (AMO/ZFO) composite nanofibers were synthesized by electrospinning
and co-precipitation and fabricated into photoanodes. It is found
that the constructed S-type heterojunction of AMO/ZFO composites effectively
inhibits the recombination of photogenerated carriers, in addition
to the benefits of more exposed active sites and a greater specific
surface area. When several properties are improved, AMO/ZFO composites
exhibit excellent photoelectrocatalytic performance. The results demonstrate
that under visible light irradiation, the photoelectrocatalytic degradation
rate of AMO/ZFO-3 to methylene blue reached 76.2% within 50 min, and
the killing rate of Salmonella was 83.6% within 80
min. The enhanced photoelectrocatalytic activity was due to the synergy
of both electrochemical and photocatalytic effects. More importantly,
after four testing cycles, AMO/ZFO-3 still has a better ability to
kill pathogenic bacteria and degrade organic dyes due to its high
stability. This work provides a feasible method for oxidizing organic
dyes and pathogenic bacteria.
Controlling the content of biogenic amines (BAs) is critical to guarantee the safety of fermented aquatic products. The degradation characteristics and application potential of amine-negative starter cultures (Virgibacillus halodenitrificans CGMCC 1.18601: G25, Virgibacillus pantothenticus CGMCC 1.18602: G38) screened from grasshopper sub shrimp paste (Gssp) were studied. The enzymes of the two strains G25 and G38 that degrade BAs were amine oxidases (AOs) located on their respective cell membranes. The conditions that promoted the AO activity of Virgibacillus spp. were NaCl concentrations 5–10%, temperature 37 °C, pH 7.0 and ethanol concentrations 0–2%. Safety assessments (antibiotic susceptibility, biofilm activity and hemolytic activity) indicated that Virgibacillus spp. do not present a risk to human health, and this isolate can be confidently recommended as safe starter cultures for the food industry. Then, the two strains were cultured separately as starters and applied to the Gssp to analyze their influence on the flavor and quality of the product. As far as the bad flavors in Gssp such as sulfur-organic and sulf-chlor were concerned, the response values in the starter groups by G25 and G38 were significantly reduced by 39% and 65%, respectively. For the ability of strains to degrade BAs in Gssp, G25 degraded 11.1% of histamine, 11.3% of tyramine, 15.5% of putrescine and 4.1% of cadaverine; G38 significantly degraded 10.1% of histamine, 21.8% of tyramine, 18.1% of putrescine and 5.0% of cadaverine. These results indicated that the selected species could be used as starter cultures for the control of BA accumulation and degradation in Gssp.
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