Electrochemical water splitting is a promising method for storing light/electrical energy in the form of H fuel; however, it is limited by the sluggish anodic oxygen evolution reaction (OER). To improve the accessibility of H production, it is necessary to develop an efficient OER catalyst with large surface area, abundant active sites, and good stability, through a low-cost fabrication route. Herein, a facile solution reduction method using NaBH as a reductant is developed to prepare iron-cobalt oxide nanosheets (Fe Co -ONSs) with a large specific surface area (up to 261.1 m g ), ultrathin thickness (1.2 nm), and, importantly, abundant oxygen vacancies. The mass activity of Fe Co -ONS measured at an overpotential of 350 mV reaches up to 54.9 A g , while its Tafel slope is 36.8 mV dec ; both of which are superior to those of commercial RuO , crystalline Fe Co -ONP, and most reported OER catalysts. The excellent OER catalytic activity of Fe Co -ONS can be attributed to its specific structure, e.g., ultrathin nanosheets that could facilitate mass diffusion/transport of OH ions and provide more active sites for OER catalysis, and oxygen vacancies that could improve electronic conductivity and facilitate adsorption of H O onto nearby Co sites.
The wavelength band near 1300 nm is attractive for many telecommunications applications, yet there are few results in silicon that demonstrate high-speed modulation in this band. We present the first silicon modulator to operate at 50 Gbps near 1300 nm. We demonstrate an open eye at this speed using a differential 1.5 V(pp) signal at 0 V reverse bias, achieving an energy efficiency of 450 fJ/bit.
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