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Daytime subambient radiative cooling provides a powerful strategy for realizing sustainable thermal management without any external energy consumption. However, in practical situations a dazzling white or silver appearance is undesirable for aesthetic and functional reasons. Therefore, developing colored radiative cooling materials is greatly significant for more potential applications but remains a big challenge so far. Here, we reported a flexible colored radiative cooler based on interferometric retroreflection-induced structural color, which resolves the conflict between a colorful appearance for aesthetics and high solar reflection for cooling. All colored radiative coolers achieve subambient cooling of 4 K even under sunshine stronger than 1000 W/m 2 , while the same color commercial paints are 9−27 K higher than the ambient. Such a flexible, scalable, and low cost colored radiative cooler is expected to replace commercial paint in a practical scenario with aesthetic and cooling requirements, enabling substantial reduction in carbon emission and energy consumption.

The end-Permian extinction is typically ascribed to massive volcanic eruptions, but direct geochemical evidence linking the two independent events is generally lacking. Zinc is an important micronutrient of marine phytoplanktons, and Zn isotope (d 66 Zn) ratios of seawater are markedly higher than those of volcanic rocks and riverine waters. We conducted high-resolution Zn concentration and Zn isotope analyses on carbonate rocks across the Permian-Triassic boundary (PTB) in the Meishan section of south China. An abrupt increase of Zn concentration and a concomitant 0.5‰ decrease in d 66 Zn occur ~35 k.y. before the mass extinction and carbon isotope (d 13 C) minima. Mass balance calculation demonstrates that a 0.5‰ negative shift in d 66 Zn within thousands of years requires rapid and massive input of isotopically light Zn from volcanic ashes, hydrothermal inputs, and/or extremely fast weathering of large igneous provinces. A positive d 66 Zn shift of as much as 1.0‰ following the mass extinction demonstrates that primary productivity recovered and reached a maximum in fewer than 360 k.y. Our finding provides insights into the marine Zn cycling across the PTB and clarifies the temporal relationship and duration of events, including intensive volcanism, carbon isotope excursion, mass extinction, and widespread ocean anoxia.

Reducing needs for heating and cooling from fossil energy is one of the biggest challenges, which demand accounts for almost half of global energy consumption, consequently resulting in complicated climatic and environmental issues. Herein, we demonstrate a high-performance, intelligently auto-switched and zero-energy dual-mode radiative thermal management device. By perceiving temperature to spontaneously modulate electromagnetic characteristics itself, the device achieves ~859.8 W m−2 of average heating power (∼91% of solar-thermal conversion efficiency) in cold and ~126.0 W m−2 of average cooling power in hot, without any external energy consumption during the whole process. Such a scalable, cost-effective device could realize two-way temperature control around comfortable temperature zone of human living. A practical demonstration shows that the temperature fluctuation is reduced by ~21 K, compared with copper plate. Numerical prediction indicates that this real zero-energy dual-mode thermal management device has a huge potential for year-round energy saving around the world and provides a feasible solution to realize the goal of Net Zero Carbon 2050.

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