ZnO thin films were deposited on a R-plane sapphire substrate. The effects of the thermal energy and the kinetic energy of the sputtered species on the growth of ZnO thin films were investigated. By varying the substrate temperature, chamber pressure, and radio frequency power, the structure of ZnO thin films was transformed from polycrystalline to epitaxial on R-plane sapphire substrates. High quality (110) ZnO epitaxial thin films were grown at the condition of 400 °C, 250 W, and 5 mTorr. According to reflection high energy electron diffraction and reflection electron microscopy observations, there were no double diffraction distortion and any other patterns. Its surface roughness observed by atomic force microscopy was about 27 nm.

The corrosion behavior of glass and glass-ceramics fabricated with silicate glass frit mixed with 50~70 wt% EAF dust in the acidic solution was analyzed by both heavy metal leaching test and microstructural observation. The crystallization temperature, Tc of glassy specimens was around 850 measured by DTA and the heat treatment temperature to crystallize a glassy specimen was selected as 950 / 1 hr. The spinel crystal peaks were found in XRD analysis for the glass containing dust > 60 wt%. For the glass-ceramics, however, the spinel peaks in a specimen containing dust > 50 wt% was found with weak willemite peaks. The glass and glass-ceramic specimens showed the first stage of corroding reaction according to Clark models in acidic solution. The glass-ceramic specimens showed much lower a heavy metal leaching concentration than that of glass specimens in the corrosion test in acidic solution of pH=2.95. Especially, the glass-ceramics containing dust 60 wt% showed a heavy metal leaching concentration of 66 % Pb, 60 % Zn and 98 % Fe lower than that of glass specimens due to crystal phases formed, thermodynamically more stable than a glass network structure. From the leaching test that more Zn ion leached out than Fe ion, the spinel crystal phase [ZnFe2O4] showed better corrosion resistant in the acidic solution than the willemite [Zn2SiO4].

Thermal behaviors of EAF dust, water-washed EAF dust, and EAF dust/heavy clay mixtures with wet mixing process were characterized by TG/ DTA analysis. The ionic concentrations of some metal ions and anions in the supernatant from water-washing process were evaluated by ICP and IC analysis. Weight loss of water-washed EAF dust above the temperature range of 1000°C was significantly decreased because of the washing effect of chloride and sulfate compounds. The variation of volatile ZnO and PbO contents were not detected in 20wt% D dust-80wt% clay sample. The wet mixing process not only enhanced the homogeneous mixing of EAF dust and clay particles, but also reduced the volatilization of heavy metals(Zn, Pb, etc.) at the high temperature range.

The dependence of composition and sintering temperature on physical properties of ALA was investigated. Mechanism of black discoloration(sometimes called black core) usually found in the interior cores of artificial lightweight aggregate was also investigated by the optical observations. As a result, the primary cause of black discoloration in the interior of the lightweight aggregate body resulting from incomplete burn-out of carbonaceous impurities and iron-containing materials.In the cross-sectional morphology of ALA, bloating phenomena as well as formation of large pores were found in the samples containing ferrous materials. By increasing content of ferrous materials, both specific gravity and water absorption have been decreased.

The artificial aggregates were fabricated from several industrial wastes such as waste white clay at 1100 ~ 1150℃/10min in a rotary kiln and its physical properties were evaluated. The water absorption, porosity and emission rate of aggregates were controlled by changing processing methods or compositions which change the microstructure of specimens. The natural aggregates showed many macro pores(120~180 ㎛), high porosity, high water absorption and low unit weight compared to artificial aggregates, while a porosity of artificial aggregates whose apparent shape is more regular was higher than that of a natural aggregates. Increasing waste white clay content in aggregates enhanced bloating during sintering, so increased the absorptivity of specimens. The void contents influenced a initial water emission and the natural aggregates showed a higher void content compared to artificial one due to their irregular shape. The artificial aggregates having shell structure showed a excellent water release control ability. Especially, for after 6 days, its water emission amount was lower than that of natural aggregates. However, artificial aggregates whose shell is removed through crushing process showed deteriorated water release ability.All rights reserved. No part of contents of this paper may be reproduced or transmitted in any form or by any means without the written permission of Trans Tech Publications Ltd, www.scientific.net.