Artificial photosynthesis using semiconductors has been investigated for more than three decades for the purpose of transferring solar energy into chemical fuels. Numerous studies have revealed that the introduction of plasmonic materials into photochemical reaction can substantially enhance the photo response to the solar splitting of water. Until recently, few systematic studies have provided clear evidence concerning how plasmon excitation and which factor dominates the solar splitting of water in photovoltaic devices. This work demonstrates the effects of plasmons upon an Au nanostructure-ZnO nanorods array as a photoanode. Several strategies have been successfully adopted to reveal the mutually independent contributions of various plasmonic effects under solar irradiation. These have clarified that the coupling of hot electrons that are formed by plasmons and the electromagnetic field can effectively increase the probability of a photochemical reaction in the splitting of water. These findings support a new approach to investigating localized plasmon-induced effects and charge separation in photoelectrochemical processes, and solar water splitting was used herein as platform to explore mechanisms of enhancement of surface plasmon resonance.

Toroidal multipoles are the subject of growing interest because of their unusual electromagnetic properties different from the electric and magnetic multipoles. In this paper, we present two new related classes of plasmonic metamaterial composed of purposely arranged of four U-shaped split ring resonators (SRRs) that show profound resonant toroidal responses at optical frequencies. The toroidal and magnetic responses were investigated by the finite-element simulations. A phenomenon of reversed toroidal responses at higher and lower resonant frequencies has also been reported between this two related metamaterials which results from the electric and magnetic dipoles interaction. Finally, we propose a physical model based on coupled LC circuits to quantitatively analyze the coupled system of the plasmonic toroidal metamaterials.

We investigate the plasmonic resonance modes and coupling effects of single silver nanobeads and silver nanobead dimers. Numerical investigation using the three-dimensional finite element method indicates that silver nanobeads exhibit two plasmonic resonances corresponding to the bonding and anti-bonding modes, respectively. The boundary symmetry on the inner and outer surfaces of the silver nanobeads can be broken by increasing the refractive indices of the cores filling the dielectric holes. It is shown that only the bonding mode can be found for low-refractive index cores, whereas both bonding and anti-bonding modes can be found for high-refractive index cores.

We propose an innovative active imaging device named gain-assisted hybrid-superlens hyperlens and examine its resolving power theoretically. This semi-cylindrical device consists of a core of semi-cylindrical super-lens and a half cylindrical outer shell of hyperlens. Both the superlens and hyperlens parts of the device are appropriately designed multi-layered metal-dielectric structures having indefinite eigenvalues of dielectric tensors. The dielectric layers of the hyperlens are doped with Coumarin, which play the role of gain medium. The gain medium is analyzed thoroughly using a generic four-level system model, and the permittivity of the gain medium is extracted from this analysis for simulating the imaging characteristics of the device. According to our simulation at wavelength of 365 nm, an excellent resolution power much better than the diffraction limit value can be achieved.

Using the curved arrangement of Au nanobumps, the scattering of surface plasmon waves are transformed into spots at desired locations and altitudes in three‐dimensional space. The light can be modulated into desired light patterns. This work is very promising for compact plasmonic circuitry, projection, live‐cell imaging, optical sensing, and holography.