No abstract

SrTiO3 cubes with tunable sizes of 160–290 nm have been synthesized by mixing TiCl4, SrCl2, and LiOH in pure ethanol or a water/ethanol mixed solution at just 70 °C for 3 h. Replacing water/ethanol with water/hexanol and water/ethylene glycol, and fine tuning the amounts of other reagents, resulted in the formation of edge-truncated cubes and {100}-truncated rhombic dodecahedra, respectively. X-ray diffraction and transmission electron microscopy characterization, supported by Rietveld refinement analysis, have revealed shape-dependent tuning in lattice parameters. The cubes display slight size-related optical band shifts, and they show clearly more blue-shifted light absorption than the other particles exposing significant {110} faces. The {100}-truncated rhombic dodecahedra are far more efficient than cubes at photodegradation of methylene blue and photocatalyzed hydrogen evolution from water in the presence of methanol. The photocatalytic activity variation should arise from different degrees of surface band bending for the {100} and {110} faces of SrTiO3, suggesting surface facet control as a strategy for enhancing photocatalyzed hydrogen production.

High-dose morphine impaired angiogenesis, increased systemic oxidative stress, and impaired mobilization of endothelial progenitor cells. This study emphasizes the potential detrimental effect of high-dose morphine on angiogenesis after systemic administration.

Defects in perovskite films and the suboptimal interface contact largely limit the performance and stability of inverted perovskite solar cells (PSCs). A simple surface post‐treatment with N‐benzyloxycarbonyl‐d‐valine (NBDV) is developed to overcome these problems. The device performance following NBDV treatment is systemically investigated. It is showed that NBDV surface post‐treatment results in the bulk restructure of the entire perovskite film and improves the film‐forming property of [6,6]‐phenyl‐C61‐butyric acid methyl ester. The grain sizes, crystallinity, trap states, cathode interfaces, as well as the built‐in field are also improved, which result in PSC performance and stability enhancement. A relatively higher power conversion efficiency (PCE) of 21.80% is reached, which is comparable to the PCE record based on single‐crystal MAPbI3. Meanwhile, the PCE of the NBDV devices can retain ≈77% and 84% of the initial value after storage for 768 h (32 days) in air and 8376 h (349 days) in N2, respectively, while the control devices only maintain ≈53% and 38% of their initial PCE values under the same exposure conditions. This work provides means to promote bulk, surface, and interface regulation toward high performance and stable inverted PSCs.

No abstract