Hybrid organic-inorganic and all-inorganic metal halide perovskite nanocrystals (PNCs) have aroused extensive attention from both academic and industrial researchers, considering their excellent performance in optoelectronic applications. Herein, we develop a facile and time-saving strategy to synthesize NHCH═NHPbBr (NHCH═NH, FA) PNCs at room temperature. Benefiting from this facile method, high-quality FAPbBr PNCs with photoluminescence quantum yield up to 76% and narrow full width at half-maxima of 20 nm can be produced on a large scale. Moreover, anion-exchange reactions run by using FAPbBr as a template, producing various PNCs with different anion constituents. By manipulating the ratios of two different anions, a series PNCs with various bright photoluminescence ranging from 452 to 646 nm could be done. On account of superior and adjustable photoluminescence over the visible spectral region, FAPbBr PNCs can be applied as a promising color-converting material in liquid-crystal display (LCD) backlight, white light-emitting diode (WLED), and inkjet printing pattern. As a proof of concept, FAPbBr PNCs with green emission were integrated in WLED and LCD backlight, accomplishing a color rendering index of 87.5 and a wide color gamut of 116%, respectively.

Angle-independent structural colors are prepared by membrane separation-assisted assembly (MSAA) method with modified reduced graphene oxide (rGO) as the substrate membrane. We show that the wrinkled and crumpled rGO laminates not only ensure uneven morphology of colloidal film but improve color saturation by decreasing coherent scattering. In addition, we study the influence of stopband position on thermal insulation property of the colloidal film for the first time. High absolute temperature difference of 6.9 °C is achieved comparing with control sample. And films with longer stopband positions indicate better thermal insulation performance because of inherent slow photon effect in photonic structure. This general principle of thermal insulation by colloidal films opens the way to a new generation of thermal management materials.

Microfluidic spinning technology (MST) has drawn much attention owing to its ideal platform for ordered fluorescent fibers, along with their large-scale manipulation, high efficiency, flexibility, and environment friendliness. Here, we employed the MST to fabricate a series of uniform fluorescent microfibers. By adjusting the microfluidic spinning parameters, the as-prepared microfibers of different diameters are successfully obtained. For more practice, these regular arranged fibers could be formed to versatile fluorescent codes by using various microfluidic chips. Also, these versatile fluorescent fibers could be further weaved into a white fluorescent film via continuous and cross-spinning process, which could be applied in a white light emitting diode (WLED) and a wearable device. Besides, we investigated the MST-directed microreactors to carry out green synthesis of CdSe quantum dots (QDs) fibers by the knot of Y-type microfluidic chip. The as-prepared CdSe QDs show nice optical property and are good candidate as phosphors in WLED. This strategy offers a facile and environment-friendly route to fluorescent hybrid microfibers and might open their potential application in optical devices, security, and fluorescent coding.

We fabricated dendrimer-modified colloids and utilized them to fabricate PC films with good mechanical strength and high performance WLEDs.