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Spiropyran (SP) and its derivatives operate between their ring opening and closing forms as a versatile molecular platform for the fluorescence detection of cations and anions, using a colour change for signalling. A functionalized SP fluorescence probe, L, was prepared and characterized. Probe L can detect Ca 2+ with a fluorescence 'turn-on' response in ethanol solution. It selectively binds Ca 2+ to form a 1:1 ligand/metal complex, which produced a new emission band centred at 604 nm. The sensing result was clearly observed by the solution colour change from colourless to pink under visible light, and from blue to red under ultraviolet light. The detection limit was calculated to be 4.53 × 10 −8 M for Ca 2+ . The probe provides another possibility that SP-based derivatives could be used for the development and detection of metal ions in environmental and physiological systems.

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Federated clouds raise a variety of challenges for managing identity, resource access, naming, connectivity, and object access control. This paper shows how to address these challenges in a comprehensive and uniform way using a data-centric approach. The foundation of our approach is a trust logic in which participants issue authenticated statements about principals, objects, attributes, and relationships in a logic language, with reasoning based on declarative policy rules. We show how to use the logic to implement a trust infrastructure for cloud federation that extends the model of NSF GENI, a federated IaaS testbed. It captures shared identity management, GENI authority services, cross-site interconnection using L2 circuits, and a naming and access control system similar to AWS Identity and Access Management (IAM), but extended to a federated system without central control.