Triplet-excited-state-involved photonic and electronic properties have attracted tremendous attention for next-generation technologies. To populate triplet states, facile intersystem crossing (ISC) for efficient exciton spin-flipping is crucial, but it remains challenging in organic molecules free of heavy atoms. Here, a new strategy is proposed to enhance the ISC of purely organic optoelectronic molecules using heteroatom-mediated resonance structures capable of promoting spin-flipping at large singlet-triplet splitting energies with the aid of the fluctuation of the state energy and n-orbital component upon self-adaptive resonance variation. Combined experimental and theoretical investigations confirm the key contributions of the resonance variation to the profoundly promoted spin-flipping with ISC rate up to ≈10 s in the rationally designed NPX (X = O or S) resonance molecules. Importantly, efficient organic ultralong room-temperature phosphorescence (OURTP) with simultaneously elongated lifetime and improved efficiency results overcoming the intrinsic competition between the OURTP lifetime and efficiency. With the spectacular resonance-activated OURTP molecules, time-resolved and color-coded quick response code devices with multiple information encryptions are realized, demonstrating the fundamental significance of this approach in boosting ISC dynamically for advanced optoelectronic applications.

The interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.

Highlights d Small molecules form a covalent bond with palmitate cysteine d Covalent engagement of cysteine inhibited TEAD4,Yap1 protein-protein interaction d Inhibition of TEAD4,Yap1 in mammalian cells blocked TEAD transcriptional activity d Small-molecule inhibition of TEAD4,Yap1 inhibited glioblastoma cell viability

The exciton dissociations and charge recombinations to a triplet state in the donor−acceptor heterojunction solar cells of [2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta-[2,1-b;3,4-b]dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] (PCPDTBT) blended with ten different fullerene derivatives are theoretically investigated by using electronic structure calculations together with a Marcus formula. The detailed discussions of available accuracy in the evaluation of all quantities entering the rate expression (driving force, electronic coupling, and internal and external reorganization energies) are provided. The results reveal that the exciton dissociations in most blends are barrierless reactions because the corresponding values of driving forces and reorganization energies are very close; however, the recombinations from the charge transfer states to the triplet state of PCPDTBT occur in the Marcus normal regime. The predicted rates for both the exciton dissociation and charge recombination are in quite good agreement with experimental measurements. In addition, as the triplet charge transfer states are formed, their recombination rates become two orders larger than those for the singlet ones and have orders similar to the exciton dissociations. It is thus expected that the triplet charge recombinations are dominant channels, whereas the singlet charge recombinations can be safely neglected because of quite small rates compared to exciton dissociation ones.