Experiment: Synthesis of BiOI microspheres:0.728 g Bi(NO 3 ) 3 •5H 2 O in 20 mL absolute ethanol in 100 mL flask and 0.249 g KI in 40 mL distilled water were prepared first. After completion of dissolution, KI solution was added drop-wise into the Bi(NO 3 ) 3 •5H 2 O solution with stir. Adjust the pH of the mixture to 7 by adding 1.5 M NH3•H2O, then, put the mixture in oil bath maintained at 80 for 3 h. The precipitates were collected by centrifugation, washed several times with distilled water and ethanol and finally dried in an oven overnight at 60 C. Finally, BiOI microspheres (diameter: 2~4 µm) were obtained. Characterization of BiOI microspheres:The scanning electron microscopy (SEM) images ( Figure S1A to Bi-O bond while the peak at 532.1 eV can be attributed to the hydroxyl groups on the surface of sample. The XPS spectrum of I 3d is shown in Figure 2C(d).The peaks with binding energy
In this work, we demonstrate cerium (Ce) based metal−organic frameworks (MOFs) combined with carbon nanotubes (CNTs) to form Ce-MOF/CNT composites as separator coating material in the Li−S battery system, which showed excellent electrochemical performance even under high sulfur loading and much better capacity retention. At the sulfur loading of 2.5 mg/ cm 2 , initial specific capacity of 1021.8 mAh/g at 1C was achieved in the Li−S cell with the Ce-MOF-2/CNT coated separator, which was slowly reduced to 838.8 mAh/g after 800 cycles with a decay rate of only 0.022% and the Coulombic efficiency of nearly 100%. Even at a higher sulfur loading of 6 mg/cm 2 , the cell based on Ce-MOF-2/CNT separator coating still exhibited excellent performance with initial specific capacity of 993.5 mAh/g at 0.1 C. After 200 cycles, the specific capacity of 886.4 mAh/g was still retained. The excellent performance is ascribed to the efficient adsorption of the Ce-MOF-2 to Li 2 S 6 species and its catalytic effect toward conversion of polysulfides, resulting in suppressed shuttle effect of polysulfides in the Li−S batteries.
The vertical composition distribution and crystallinity of photoactive layers are considered to have critical roles in photovoltaic performance. In this concise contribution, the layer-by-layer (LBL) solution process is used to fabricate efficient polymer solar cells. The results show that the vertical composition distribution can be finely regulated via employing solvent additive 1,8-diiodooctane (DIO). The favorable vertical component distribution in tandem with improved crystallinity induced by DIO contributes to the efficient exciton dissociation, charge transportation and extraction, and limited charge recombination loss. Therefore, the optimized LBL devices yield an efficiency of 16.5%, which is higher than that of the control bulk heterojunction solar cells with an efficiency of 15.8%. Importantly, the ternary solar cells based on PM6/ Y6:PC 71 BM LBL active layers demonstrate a promising efficiency of >17%, which is the record efficiency for LBL solar devices reported to date. These findings make clear that the solvent additive-assisted LBL solution process has broader implications for the further optimization of solar cells.
HIGHLIGHTS• Recent advances of micro/nanomotors in the field of cancer-targeted delivery, diagnosis, and imaging-guided therapy are summarized.• Challenges and outlook for the future development of micro/nanomotors toward clinical applications are discussed.ABSTRACT Micro/nanomotors have been extensively explored for efficient cancer diagnosis and therapy, as evidenced by significant breakthroughs in the design of micro/nanomotors-based intelligent and comprehensive biomedical platforms. Here, we demonstrate the recent advances of micro/nanomotors in the field of cancer-targeted delivery, diagnosis, and imaging-guided therapy, as well as the challenges and problems faced by micro/nanomotors in clinical applications. The outlook for the future development of micro/nanomotors toward clinical applications is also discussed. We hope to highlight these new advances in micro/nanomotors in the field of cancer diagnosis and therapy, with the ultimate goal of stimulating the successful exploration of intelligent micro/nanomotors for future clinical applications.
Synthetic micro/nanomotors (MNMs) are a particular class of micrometer or nanometer scale devices with controllable motion behavior in solutions by transferring various energies (chemical, optical, acoustic, magnetic, electric, etc.) into mechanical energy. These tiny devices can be functionalized either chemically or physically to accomplish complex tasks in a microcosm. Up to now, MNMs have exhibited great potential in various fields, ranging from environmental remediation, nanofabrication, to biomedical applications. Recently, light-driven MNMs as classic artificial MNMs have attracted much attention. Under wireless remote control, they can perform reversible and repeatable motion behavior with immediate photoresponse. Photocatalytic micro/nanomotors (PMNMs) based on photocatalysts, one of the most important light-driven MNMs, can utilize energy from both the external light source and surrounding chemicals to achieve efficient propulsion. Unlike other kinds of MNMs, the PMNMs have a unique characteristic: photocatalytic property. On one hand, since photocatalysts can convert both optical and chemical energy inputs into mechanical propulsion of PMNMs via photocatalytic reactions, the propulsion generated can be modulated in many ways, such as through chemical concentration or light intensity. In addition, these PMNMs can be operated at low levels of optical and chemical energy input which is highly desired for more practical scenarios. Furthermore, PMNMs can be operated with custom features, including go/stop motion control through regulating an on/off switch, speed modulation through varying light intensities, direction control through adjusting light source position, and so forth. On the other hand, as superoxide radicals can be generated by photocatalytic reactions of activated photocatalysts, the PMNMs show great potential in environment remediation, especially in organic pollutant degradation. In order to construct more practical PMNMs for future applications and further extend their application fields, the ideal PMNMs should be operated in a fully environmentally friendly system with strong propulsion. In the past decade, great progress in the construction, motion regulation, and application of PMNMs has been achieved, but there are still some challenges to realize the perfect system. In this Account, we will summarize our recent efforts and those of other groups in the development toward attractive PMNM systems. First, we will illustrate basic principles about the photocatalytic reactions of photocatalysts and demonstrate how the photocatalytic reactions affect the propulsion of PMNMs. Then, we will illustrate the construction strategies for highly efficient and biocompatible PMNMs from two key aspects: (1) Improvement of energy conversion efficiency to achieve strong propulsion of PMNMs. (2) Expansion of the usable wavelengths of light to operate PMNMs in environment-friendly conditions. Next, potential applications of PMNMs have been described. In particular, environment remediation has taken major att...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.