Main observation and conclusion With the increasing demand of sustainable and eco‐friendly resources, it is very attractive to use waste leaves for activated carbon (AC) preparation that can be used in supercapacitors. Considering the practically collected leaves are commonly in mixed nature, and extra efforts are needed to sort these mixtures, we here report the first preparation of AC using mixed leaves from different plants, including Platanus acerifolia (PA), Firmiana platanifolia (FP) and Pistia stratiotes (PS), and compared the results with single leaves‐derived AC materials. These leave‐derived AC samples were characterized with FESEM, EDS, FTIR and Raman spectroscopy, and electrochemical tests. The AC derived from mixed leaves (PA3FP1PS2AC) showed a good specific capacitance of 246 F·g−1 at 1 A·g−1 in aqueous 3 mol·L–1 KOH. This sample further showed the largest specific capacitance of 201 F·g−1 at 5 A·g−1, as compared with the non‐mixed AC samples, and a good stability of 100.0% capacitance retention over 1000 cycles. Utilizing mixed leaves for AC preparation is not only demonstrated to be a promising approach of low cost and high‐performance AC production for supercapacitor applications, but may also help environmental protection by reducing the invasive species problem.
The circumstances of transferred electrons across organic/inorganic interfaces have attracted intensive interest because of the distinctive electronic structure properties of those two components. Leveraging ab initio nonadiabatic molecular dynamics methods in conjunction with spin dynamics induced by spin−orbital couplings (SOCs), this study reports two competitive channels during photoinduced dynamical processes in the prototypical ZnPc/monolayer MoS 2 heterojunction. Interestingly, the electron-transfer and relaxation processes occur simultaneously because of the enhancement of electron−phonon couplings and expansion of dynamical pathways by SOCs, suggesting that the electron-transfer rate and relaxation processes can be tuned by SOCs, hence yielding the performance promotion of photovoltaic and photocatalytic devices. Additionally, approximately half of the transferred electrons flip their spin within 1.6 ps because of strong SOCs in MoS 2 , achieving great agreement with experimental measurements. This investigation provides instructive perspectives for designing novel devices and applications based on organic/inorganic heterojunctions, demonstrating the importance of spin dynamics simulations in exploring sophisticated photoinduced processes in materials.
This paper proposed a framework and an algorithm for identifying communities in dynamic social networks. In order to handle the drawbacks of traditional approaches for social network analysis, we utilize the community similarities and infrequent change of community members combined with community structure optimization to develop a Group-based social community identification model to analyze the change of social interaction network with multiple time steps. According to this model ,we introduced a greed-cut algorithm and depthsearch-first approach and combine them to develop a new algorithm for dynamic social interaction network recognition (called ADSIN). In addition, we conduct experiments on the dataset of Southern Women, the experiment results validate the accuracy and effectiveness of ADSIN.
To enhance the fluorescence efficiency of semiconductor nanocrystal quantum dots (QDs), strategies via enhancing photo-absorption and eliminating non-radiative relaxation have been proposed. In this study, we demonstrate that fluorescence efficiency of molybdenum disulfide quantum dots (MoS 2 QDs) can be enhanced by single-atom metal (Au, Ag, Pt, Cu) modification.Four-fold enhancement of the fluorescence emission of MoS 2 QDs is observed with single-atom Au modification. The underlying mechanism is ascribed to the passivation of non-radiative surface states owing to the new defect energy level of Au in the forbidden band that can trap excess electrons in n-type MoS 2 , increasing the recombination probability of conduction band electrons with valence band holes of MoS 2 . Our results open an avenue for enhancing the fluorescence efficiency of QDs via the modification of atomically dispersed metals, and extend their scopes and potentials in a fundamental way for economic efficiency and stability of single-atom metals.
To enhance the fluorescence efficiency of semiconductor nanocrystal quantum dots (QDs), strategies via enhancing photo-absorption and eliminating non-radiative relaxation have been proposed. In this study, we demonstrate that fluorescence efficiency of molybdenum disulfide quantum dots (MoS 2 QDs) can be enhanced by single-atom metal (Au, Ag, Pt, Cu) modification.Four-fold enhancement of the fluorescence emission of MoS 2 QDs is observed with single-atom Au modification. The underlying mechanism is ascribed to the passivation of non-radiative surface states owing to the new defect energy level of Au in the forbidden band that can trap excess electrons in n-type MoS 2 , increasing the recombination probability of conduction band electrons with valence band holes of MoS 2 . Our results open an avenue for enhancing the fluorescence efficiency of QDs via the modification of atomically dispersed metals, and extend their scopes and potentials in a fundamental way for economic efficiency and stability of single-atom metals.
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