Marine mussels harness catechol-rich foot proteins with hierarchically assembled nanostructures to achieve robust adhesion in the dynamic underwater environment.
Optically
bright lead halide perovskite nanocrystals of different
morphologies ranging from nanocubes to flat nanoplatelets to elongated
nanowires have been reported. The morphology of the nanocrystals is
expected to affect various properties such as the band edge energy
and the electron–hole exchange interaction. However, aside
from nanocubes, the investigation of optical properties in the lead
halide perovskite nanocrystals of different morphologies at the single
emitter level has been lacking. We have performed optical spectroscopy
in single CsPbBr3 nanoplatelets and observed single photon
emission without blinking. Furthermore, the photoluminescence emission
exhibits excitonic fine structure peaks similar to what has been previously
observed in nanocubes. Our work stimulates further investigations
into the excitonic and quantum optics properties when the lateral
size and morphology can be further controlled in lead halide perovskite
nanocrystals.
Lead‐free halide double perovskites (A2BIBIIIX6) with attractive optical and electronic features are considered to be a promising candidate to overcome the toxicity and stability issues of lead halide perovskites (APbX3). However, their poor absorption profiles limit device performance. Here the absorption band edge of Cs2AgBiBr6 double perovskite to the near‐infrared range is significantly broadened by developing doped double perovskites, Cs2(Ag:Cu)BiBr6. The partial replacement of Ag ions by Cu ions in the crystal lattice is confirmed by the X‐ray photoelectron spectroscopy (XPS) and solid‐state nuclear magnetic resonance (ssNMR) measurements. Cu doping barely affects the bandgap of Cs2AgBiBr6; instead it introduces subbandgap states with strong absorption to the near‐infrared range. More interestingly, the near‐infrared absorption can generate band carriers upon excitation, as indicated by the photoconductivity measurement. This work sheds new light on the absorption modulation of halide double perovskites for future efficient optoelectronic devices.
Hybrid graphene-PbS quantum dot devices are fabricated on an n-type silicon substrate capped with a thin SiO2 layer and are characterized by photoelectrical measurements. It is shown that the resistance of the graphene channel in the devices exhibits detectable changes when a laser beam is switched on and off on the quantum dots. The model that explains the observed photoresponse phenomenon is illustrated. We also show that the photoresponse signal, i.e., the photoinduced change in the resistance of the graphene channel can be tuned in both magnitude and sign with a voltage applied to the back gate of the devices and is related to the derivative of the transfer characteristics of the graphene channel. Our work shows that the simple hybrid graphene-PbS quantum dot devices can be employed for photodetection applications.
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