Being cognizant of modern electronic devices, the scientists are continuing to investigate renewable green‐energy resources for a decade. Amid different energy harvesting systems, the triboelectric nanogenerators (TENGs) have been found to be the most promising mechanical harvesting technology and have drawn attention to generate electrical energy. Thanks to its instant output power, choice to opt for wide‐ranging materials, low maintenance cost, easy fabrication process and environmentally friendly nature. Due to numerous working modes of TENGs, it is dedicated to desired application at ambient conditions. In this review, an advance correlation of TENGs have been explained based on the variety of nanostructures, including 0D, 1D, 2D, 3D, metal organic frameworks (MOFs), coordination polymers (CPs), covalent organic frameworks (COFs), and perovskite materials. Moreover, an overview of previous and current perspectives of various nanomaterials, synthesis, fabrication and their applications in potential fields have been discussed in detail.
The
development of a MOFs-derived multilevel hierarchy
in a single
step still remains a challenging task. Herein, we have synthesized
novel Cu-MOF via a slow diffusion method at ambient temperature and
further utilized it as a precursor source for MOF-derived multilevel
hierarchy (Cu/Cu
x
O@NC, x = 1 and 2). This studies suggest that the organic ligands served
as a source of an N-doped carbon matrix encapsulated with metal oxide
nanoparticles which were confirmed by various characterization techniques;
further BET analysis reveals a surface area of 178.46 m2/g. The synthesized multilevel hierarchy was utilized as an electro-active
material in a supercapacitor that achieved a specific capacitance
of 546.6 F g–1 at a current density of 1 A g–1 with a higher cyclic retention of 91.81% after 10 000
GCD cycles. Furthermore, the ASC device was fabricated using Cu/Cu
x
O@NC as the positive electrode and carbon
black as the negative electrode and utilized to enlighten the commercially
available LED bulb. The fabricated ASC device was further employed
for a two-electrode study which achieved a specific capacitance of
68 F g–1 along with a comparable energy density
of 13.6 Wh kg–1. Furthermore, the electrode material
was also explored for the oxygen evolution reaction (OER) in an alkaline
medium with a low overpotential of 170 mV along with a Tafel slope
of 95 mV dec–1 having long-term stability. The MOF-derived
material has high durability, chemical stability, and efficient electrochemical
performance. This work provides some new thoughts for the design and
preparation of a multilevel hierarchy (Cu/Cu
x
O@NC) via a single precursor source in a single step and explored
multifunctional applications in energy storage and an energy conversion
system.
The overuse of antibiotics in recent years presents a huge challenge to society for their removal from the environment. The prolonged presence of antibiotics as environmental pollutants results in the...
Covalent organic frameworks (COFs), a distinguished class of porous materials exhibiting precise modularity and crystallinity, and two-dimensional (2D) MXenes, a highly conductive, atomic layered transition metal carbides or nitrides or carbonitrides, are the two fascinating classes of advanced materials that have been intensively researched for energy storage recently. Thanks to the high surface area and porosity of COFs and high electrical conductivity coupled with highly redox active surfaces of MXenes, they have shown great potential in the energy storage applications such as batteries and supercapacitors. However, their electrochemical performance is limited by several inherent issues such as the restacking tendency of MXene sheets and low conductivity of COFs, when applied individually. Combining MXenes and COFs into heterostructures and their use as a single electrode helps in overcoming challenges for improving the energy storage capability. The current perspective intends to provide an overview of designing such COF/MXene heterostructures in the context of the energy storage applications. The research gaps that exist in designing COF/MXene heterostructures and the governing factors for improving the energy storage capability have also been highlighted as opportunities.
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