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The influence of online public opinion on agricultural product safety on the society is increasing. In order to correctly guide the direction of online public opinion on agricultural products, help the agricultural sector turn from passive to active public opinion, timely prevent the spread of negative public opinion, and reduce the negative impact on public opinion hot events, it is especially important to improve the ability of monitoring agricultural products’ network public opinion. This research is based on big data technology to develop an agricultural products’ network public opinion monitoring system that can collect, process, and analyze data in real time, discover and track hot topics, and calculate and visualize the polarity of public sentiment. The use of big data technology to increase the processing speed aims to strengthen the public’s supervision of the public opinion on the network security of agricultural products and provide an effective basis of the decision-making of relevant departments.

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High-quality P6322 Mn2N0.86 samples were synthesised using a high-pressure metathesis reaction, and the properties of the material were investigated. The measurements revealed that the Vickers hardness was 7.47 GPa, which is less than that predicted by commonly used theoretical models. At low air pressure, Mn2N0.86 and MnO coexist at 500 to 600 °C, and by excluding air, we succeeded in producing Mn4N by heating Mn2N0.86 in nitrogen atmosphere; we carefully studied this process with thermogravimetry and differential scanning calorimetry (TG-DSC). This gives a hint that to control temperature, air pressure and gas concentration might be an effective way to prepare fine Mn-N-O catalysis. Magnetic measurements indicated that ferromagnetism and antiferromagnetism coexist within Mn2N0.86 at room temperature and that these magnetic properties are induced by nitrogen vacancies. Ab intio simulation was used to probe the nature of the magnetism in greater detail. The research contributes to the available data and the understanding of Mn2N0.86 and suggests ways to control the formation of materials based on Mn2N0.86.