We for the first time report electrochemical potassium insertion in graphite in a nonaqueous electrolyte, which can exhibit a high reversible capacity of 273 mAh/g. Ex situ XRD studies confirm that KC36, KC24, and KC8 sequentially form upon potassiation, whereas depotassiation recovers graphite through phase transformations in an opposite sequence. Graphite shows moderate rate capability and relatively fast capacity fading. To improve the performance of carbon K-ion anodes, we synthesized a nongraphitic soft carbon that exhibits cyclability and rate capability much superior to that of graphite. This work may open up a new paradigm toward rechargeable K-ion batteries.

Energy storage and conversion remain signifi cantly challenging to the research community. Among the candidates, lithium-ion batteries show great attraction and have been used in a wide range of applications, from small electronic devices, such as mobile phones and notebook computers, to increasing numbers of electric vehicles and large-scale energy storage equipments. [1][2][3][4][5][6] However, the relatively high cost of lithium resources shows the potential problems in terms of the long-term and large-scale applications of lithium-ion batteries. Lithium resources are limited; lithium makes up about 0.0065% of the earth ′ s crust and is unevenly distributed in South America. Thus, development of alternative storage devices is not only desirable but also necessary. Given this background, intense interest in the use of sodium-ion batteries particularly for largescale energy storage has recently been rekindled. Sodium, an element of electrochemical equivalence and proper potential, could be used as a substitute for lithium to meet the demands of rechargeable batteries. Furthermore, the sodium resources are considered to be unlimited and sodium salts widely exist in the sea. Therefore, sodium-ion batteries demonstrate the potential to substitute for lithium-ion batteries in the particular application in large-scale energy storage for renewable solar and wind power as well as smart grid. [ 7 , 8 ] Tremendous attention has been paid to sodium-ion batteries in recent years. Many electrode materials, such as Na x CoO 2 , [ 9 ] NaCrO 2 , [ 10 ] Na 1.0 Li 0.2 Ni 0.25 Mn 0.75 O δ , [ 11 , [ 17 ] hard carbon [ 13 , 18 , 19 ] and TiO 2 [ 20 ] have been investigated for application in sodium-ion batteries. Very recently, we reinvestigated the sodium ion insertion/extraction into/from Na 3 V 2 (PO 4 ) 3 with a NASICON structure. [ 21 ] The NASICON structure features a highly covalent three-dimensional framework that generates large interstitial spaces through which sodium ions may diffuse. [22][23][24] Our previous study was the fi rst to demonstrate that carbon coating can signifi cantly improve its sodium storage performance. [ 21 ] Carbon-coated Na 3 V 2 (PO 4 ) 3 electrodes show two fl at plateaus at 3.4 V and 1.6 V vs. Na + / Na, respectively. The voltage plateau located at 3.4 V is relatively higher than that of other cathode materials for sodium-ion batteries in recent reports. [9][10][11][12][13][14][15] However, the coulombic efficiency of the Na 3 V 2 (PO 4 ) 3 electrode in a half-cell is not as high as 99.5%, and does not even increase after the fi rst cycle, [ 21 ] likely because of the NaClO 4 /PC electrolyte used. Moreover, the storage capacity could also be enhanced by decreasing the carbon content of the composite and using optimized electrolyte system. In this contribution, Na 3 V 2 (PO 4 ) 3 /C nanocomposites with different carbon contents were prepared by a one-step solid state reaction and evaluated in different electrolyte systems. It was found that the sodium storage performance in terms of capacity...

Hard carbon microspheres (HCS) exhibit a highly reversible capacity of 262 mAh g−1 for K‐ion batteries. They present a superior rate capability for K‐ions to Na‐ions, where at 2C, HCS/K cells deliver 190 mAh g−1 in contrast to 97 mAh g−1 from HCS/Na cells. It is determined that the K‐ion diffusion coefficient of HCS is higher than that of Na‐ions.