The Liujiawa site is located in the Agricultural-Nomadic Transitional Zone in Northern China (ANTZNC), inhabited during the early Spring and Autumn Period (770-476 BC). Little is known about the diets of its inhabitants or agricultural management practices due to scant historical descriptions. In this study, lipid analysis was conducted on pottery sherds collected from two residential areas within the Liujiawa site. The results offer direct evidence for the processing of millet and ruminant and non-ruminant carcass products by the commoners of the Liujiawa community. The individual δ 13 C values of fatty acids with positive fluctuation indicate that some ruminant animals and pigs were fed C 4 plants as fodder. The routine consumption of ruminant meat by the common inhabitants also reflects a more diverse food source than that proposed in historical descriptions that have suggested dietary heterogeneity between the upper and lower classes: cattle or ovicaprid meat was not a singular privilege enjoyed by the noble classes. On the contrary, commoners also consumed the meat as a food source. Moreover, direct evidence of dairy processing has been found for the first time in pottery residues from an archaeological site within ANTZNC, strongly indicating that milk had been incorporated into the diet as an additional source of food.

Cosmetics have a long history in China, but their origins remain unclear. Cosmetic industry potentially originated in the , but little is known about the early manufacture and use of cosmetics. The Liujiawa site, located on the southern edge of the Loess Plateau in northern China, was the late capital of the ancient Rui state in the early to mid-Spring and Autumn Period. During the excavation, a sealed small and exquisite container with suspected cosmetic use was unearthed from tomb M49 belonging to a male associated with the aristocratic class. We report in this paper the multidisciplinary application of ATR-FTIR, XRD, SEM, stable isotope analysis, GC-MS and GC-C-IRMS analysis of the residue inside the container, demonstrating that the residue, which was made of ruminant adipose fat mixed with monohydrocalcite from cave moonmilk, was likely used as cosmetic face cream by the nobleman of the Rui state. This study provides an early example of cosmetic production in China, and, together with the prevalence of similar cosmetic containers during this period,

Lead white is one of the most important pigments in human history, and its synthesis has promoted the development of art and cosmetics. The corrosion approach to synthesize lead white appeared in Greece during the fourth century BCE, and since then lead white has been produced on a large-scale and widely used in painting and cosmetics across Europe. However, when and how synthetic lead white appeared in east Eurasia and whether it was also involved with beauty remained unclear. Here, we investigate some white cosmetic residues from the Liangdaicun site during the eighth century BCE in northern China through FTIR, XRD, SEM-EDS, radioactive and stable carbon isotope analyses. The results show that these residues were the earliest synthesized lead white in the world to date, which was produced by the precipitation method in solution distinct from the corrosion method practiced in ancient Greece. Thus, the synthesis of lead white should have evolved independently in east and west Eurasia during the first millennium BCE. The mass production of synthetic lead white with lower cost promoted the widespread use of white makeup in China and the Mediterranean World, which triggered a cosmetic revolution and highlighted that the pursuit of beauty stimulated the development of chemistry in human history, especially the earliest wet chemistry practice in China.

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