The
manipulation of magnetism provides a unique opportunity for
the development of data storage and spintronic applications. Until
now, electrical control, pressure tuning, stacking structure dependence,
and nanoscale engineering have been realized. However, as the dimensions
are decreased, the decrease of the ferromagnetism phase transition
temperature (T
c) is a universal trend
in ferromagnets. Here, we make a breakthrough to realize the synthesis
of 1 and 2 unit cell (UC) Cr2Te3 and discover
a room-temperature ferromagnetism in two-dimensional Cr2Te3. The newly observed T
c increases strongly from 160 K in the thick flake (40.3 nm) to 280
K in 6 UC Cr2Te3 (7.1 nm). The magnetization
and anomalous Hall effect measurements provided unambiguous evidence
for the existence of spontaneous magnetization at room temperature.
The theoretical model revealed that the reconstruction of Cr2Te3 could result in anomalous thickness-dependent T
c. This dimension tuning method opens up a new
avenue for manipulation of ferromagnetism.
Silk has outstanding
mechanical properties and biocompatibility.
It has been used to fabricate traditional textiles for thousands of
years and can be produced in large scale. Silk materials are potentially
attractive in modern textile electronics. However, silk is not electrically
conductive, thus limiting its applications in electronics. Moreover,
regenerated silk is generally rigid and brittle, which hinder post
processing. Here we report the fabrication of conductive silk wire
in which carbon nanotube (CNT) yarns are wrapped with fluffy and flexible
silk nanofiber films. The silk nanofiber film was prepared by electrospinning
and then wrapped around a rotating CNT yarn in situ. The obtained
silk-sheathed CNT (CNT@Silk) wire has an insulating sheath, which
protects the body against electrical shock. In addition, the fabricated
wires exhibit a high electrical conductivity (3.1 × 104 S/m), good mechanical strength (16 cN/tex), excellent flexibility,
and high durability. More importantly, the wires have an extremely
low density (2.0–7.8 × 104 g/m3), which is
2 orders of magnitude lower than that of the traditional metal wire
(for example, Cu). Moreover, the wires display a good resistance to
humidity, and a simple post treatment can make the wires splash-resistant,
thereby expanding its applications. On the basis of these features,
we demonstrate the use of the lightweight CNT@Silk wires in smart
clothes, including electrochromism and near-field communication.
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