Conventional oil sewage treatment methods can achieve satisfactory removal efficiency, but energy consumption problems during the process of oil sewage treatment are worth attention. The integration of a constructed wetland reactor and a microbial fuel cell reactor (CW-MFC) to treat oil-contaminated wastewater, compared with a microbial fuel cell reactor (MFC) alone and a constructed wetland reactor (CW) alone, was explored in this research. Performances of the three reactors including chemical oxygen demand (COD), oil removal, and output voltage generation were continuously monitored. The COD removals of three reactors were between 73% and 75%, and oil removals were over 95.7%. Compared with MFC, the CW-MFC with a MnO2 modified cathode produced higher power density and output voltage. Maximum power densities of CW-MFC and MFC were 3868 mW/m3 (102 mW/m2) and 3044 mW/m3 (80 mW/m2), respectively. The plants in CW-MFC play a positive role for reactor cathode potential. Both plants and cathode modification can improve reactor performance of electricity generation.
Constructed wetland (CW) is a low cost and easy operation process for wastewater treatment, while filler clogging is one of the disadvantages for this technology. Using activated carbon as the filler, a regular CW and an integration of constructed wetland with microbial fuel cell (CW-MFC) were constructed. After continuous operation of four months, specific surface area and pore size distribution of the activated carbon were analyzed. The specific surface area of the fresh activated carbon was 133.8 m2/g, while the filler in the CW and CW-MFC systems had specific surface area of 38.1 m2/g and 58.2 m2/g. The surface decrease of the CW-MFC filler was 21% lower than that of CW filler. Comparing with the regular CW, the filler in the CW-MFC was more clogging resistant. The alleviation of the filler clogging in CW-MFC may be caused by the micro-electric field as the function of MFC. CW-MFC is a promising microbial electrochemical technology for wastewater treatment and filler clogging resistant, there are some detailed issues deserve to be further researched.
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