a-Si/SiO2
multilayers with different a-Si sublayer thicknesses were prepared by plasma enhanced
chemical vapour deposition (PECVD). An intermediate phase silicon structure
(IPSS), which is intermediate in order between the continuous random network
amorphous phase and the well ordered crystalline phase, was discovered in the a-Si
sublayers near the crystallization onset temperatures through Raman scattering and
cross-section high resolution transmission electron microscopy (HRTEM). A strong broad
photoluminescence (PL) band, consisting of two peaks centred at 773 nm and
863 nm respectively, was observed with the formation of the IPSS. Based on the
analysis of the temperature dependence of PL, the strong PL emission bands
centred at 863 and 773 nm are ascribed to the structural defects inside the IPSS and
Si = O
at the surface of the IPSS, respectively.
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