Foam injection molding (FIM) is an advanced technology for preparing lightweight plastic foams, but its inferior mechanical performance remains a challenge. In this study, microcellular injection-molded β-polypropylene (β-PP) foams with high ductility were successfully prepared by combing the β-nucleating agent with controllable temperature field. Foaming results showed that the microcellular β-PP foams exhibiting a cell size of about 8 μm and cell density over 10 8 cells/cm 3 were prepared with a crystalline diameter approximately 5 μm, while PP foams had a rather large cell size approximately 150 μm and low cell density of 10 5 cells/cm 3 with 30 μm crystalline size. As a result, this significant improvement in cell structure as well as the crystalline size lead to a significant increment of 86% for the ductility of β-PP foams. This work offers a facile strategy to prepare injection-molded foams with desirable mechanical properties for their wide range of applications, such as automotive construction and consumer electronics.
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