Rapid developments in the electric industry have promoted an increasing demand for lithium resources. Lithium in salt lake brines has emerged as the main source for industrial lithium extraction, owing to its low cost and extensive reserves. The effective separation of Mg 2? and Li ? is critical to achieving high recovery efficiency and purity of the final lithium product. This paper summarizes Mg 2? /Li ? separation materials and methods in the field of lithium recovery from salt lake brines. The review begins with an introduction to the global distribution and demand for lithium resources, followed by a description of the materials used in various separation techniques, including precipitation, adsorption, solvent extraction, nanofiltration membrane, electrodialysis, and electrochemical methods. A comparison, analysis, and outlook of such methods are comprehensively discussed in terms of principles, mechanisms, synthesis/operation, development, and industrial applications. We conclude with a presentation of challenges and insights into the future directions of lithium extraction from salt lake brines. A combination of the advantages of various materials is the most logical step toward developing novel methods for extracting lithium from brines with high separation selectivity, stability, low cost, and environmentally friendly characteristics.
Organic montmorillonite (MMT) modified by 1,3-dihexadecyl-3H-benzimidazolium bromide (Bz) was used to prepare polyphenylene sulfide (PPS)/MMT composites by melting intercalation. The PPS/MMT composites showed mixed morphology, being comprised of exfoliated and intercalated structures with slight agglomerates. The tensile property of PPS/MMT composites was significantly improved due to the good dispersion of the MMT nanolayers. The test results showed that the tensile strength retention of PPS/MMT composites was higher than that of pure PPS after the oxidation treatment. Moreover, FTIR and XPS analyses were also used to evaluate the oxidation resistance of PPS composites. The FTIR analysis confirmed that adding MMT could better limit the damage of the C-S group and retard the generation of sulfuryl groups (-SO 2 -) during the oxidation treatment compared to pure PPS. The XPS analysis also suggested that the addition of MMT could reduce the chemical combination of the elements sulfur (S) and oxygen (O) during oxidation treatment. Furthermore, the MMT nanolayers could also promote the transfer of S from a C-S bond into an -SO 2 -group.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.