Organic bulk heterojunction fullerence (C 60 ) doped 5, 6, 11, 12-tetraphenylnaphthacene (rubrene) as the high quality charge generation layer (CGL) with high transparency and superior charge generating capability for tandem organic light emitting diodes (OLEDs) is developed. This CGL shows excellent optical transparency about 90%, which can reduce the optical interference effect formed in tandem OLEDs. There is a stable white light emission including 468 nm and 500 nm peaks from the blue emitting layer and 620 nm peak from the red emitting layer in tandem white OLEDs. A high efficiency of about 17.4 cd/A and CIE coordinates of (0.40, 0.35) at 100 cd/m 2 and (0.36, 0.34) at 1000 cd/m 2 have been demonstrated by employing the developed CGL, respectively.
Microbial fuel cells (MFC) are expected to alleviate the energy crisis and environmental pollution. However, both the slow oxygen reduction reaction (ORR) kinetics and the formation of biofilm on the cathode prevent the efficient operation of MFC. Herein, zeolitic imidazole framework (ZIF)‐derived Ag−Fe−N/C catalysts with good electrocatalytic activity are developed by a synthetic strategy of chemisorption, calcination, and photo‐deposition. The optimal Ag−Fe−N/C‐2 has a half‐wave potential (E1/2) of 0.87 V vs. RHE in 0.1 M KOH. The MFC assembled as a cathode exhibits excellent power generation with a maximum power density of 523±7 mW m−2 and long‐term stability, which is better than commercial Pt/C. In addition, the Ag−Fe−N/C‐2 catalyst has the antibacterial ability, which affects the microbial community structure on the cathode biofilm. The results indicate that Ag−Fe−N/C as a bifunctional cathode catalyst with excellent electrocatalytic and antibacterial activity is beneficial to the efficient and long‐term stable operation of MFC.
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