Organic ultralong room temperature phosphorescence (OURTP) materials with photophysical properties sensitive to external stimulus are highly attractive for advanced applications.H owever,m ost OURTPm olecules are in crystal and OURTP materials with good practicability and stimulusresponsive character are hard to be achieved. Here,wereport, for the first time,the highly efficient, ultralong-lived and deepblue OURTPmaterials by simply doping boron phosphor into cyanuric acid host. Host-guest OURTP composites with abundant and tunable H-bond network are highly stable in air with ultralong lifetime of 5.08 satroom temperature.They are sensitive to water,which can strength the H-bond network to significantly enhance OURTP quantum yield from 16.1 %to 37.6 %. Anti-counterfeiting paper was easily prepared for water-jet printing;t he jet-printed high-resolution OURTP patterns can be easily erased by solvent fuming for another printing/erasing cycle with high reversibility.
Circularly polarized organic afterglow (CPOA) with both long-lived room-temperature phosphorescence (RTP) and circularly polarized luminescence (CPL) is currently attracting great interest, but the development of multicolor-tunable CPOA in a single-component material remains a formidable challenge. Here, we report an efficient strategy to achieve multicolor CPOA molecules through chiral clusterization by implanting chirality center into non-conjugated organic cluster. Owing to excitation-dependent emission of clusters, highly efficient and significantly tuned CPOA emissions from blue to yellowish-green with dissymmetry factor over 2.3 × 10−3 and lifetime up to 587 ms are observed under different excitation wavelengths. With the distinguished color-tunable CPOA, the multicolor CPL displays and visual RTP detection of ultraviolent light wavelength are successfully constructed. These results not only provide a new paradigm for realization of multicolor-tunable CPOA materials in single-component molecular systems, but also offer new opportunities for expanding the applicability of CPL and RTP materials for diversified applications.
Organic
ultralong room temperature phosphorescence (OURTP) materials
having stimuli-responsive attributes have attracted great attention
due to their great potential in a wide variety of advanced applications.
It is of fundamental importance but challengeable to develop stimuli-responsive
OURTP materials, especially such materials with modulated optoelectronic
properties in a controlled manner probably due to the lack of an authentic
construction approach. Here, we propose an effective strategy for
OURTP materials with controllably regulated stimuli-responsive properties
by engineering the resonance linkage between flexible chain and phosphor
units. A quantitative parameter to demonstrate the stimuli-responsive
capacity is also established by the responsivity rate constant. The
designed OURTP materials demonstrate efficient photoactivated OURTP
with lifetimes up to 724 ms and tunable responsivity rate constants
ranging from 0.132 to 0.308 min–1 upon continuous
UV irradiation. Moreover, the applications of stimuli-responsive resonance
OURTP materials have been illustrated by the rewritable paper for
snapshot and Morse code for multiple information encryption. Our works,
which enable the accomplishment of OURTP materials capable of on-demand
manipulated optical properties, demonstrate a viable design to explore
smart OURTP materials, giving deep insights into the dynamically stimuli-responsive
process.
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