This study aimed to investigate the applicability of new low-cost activated carbons with a high surface area prepared by KOH chemical activation of jujube shells (denoted JSAC) as adsorbent of Chemical Organic Demand (COD) from wastewater.The prepared activated carbon is characterized by various physical-chemical methods to determine their morphological, textural and chemical characterization, including nitrogen adsorption-desorption isotherms, Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Boehm titration method and the pH of the point of zero charge (pH PZC ).Then they were used as an adsorbent for the removal of COD from wastewater collected from Fez area. Adsorption equilibrium and kinetic data were determined and fitted to several adsorption isotherms and kinetics models, respectively. The results showed that the Langmuir isotherm fitted well the equilibrium data of COD on JSAC adsorbent; whereas, the kinetic data were best fitted by the pseudo-second-order model. This adsorbent showed the highest removal efficiency for COD (72%) and the grey colour of the wastewater (83%) for an optimum dose of 0.5 g JSAC . L -1 . Results from the study showed that JSAC activated carbon could be utilized as an effective and less expensive adsorbent for the removal of COD in wastewater.
This study aimed to investigate the applicability of new low-cost activated carbons with a high surface area prepared by KOH chemical activation of jujube shells (denoted JSAC) as adsorbent of Chemical Organic Demand (COD) from wastewater.The prepared activated carbon is characterized by various physical-chemical methods to determine their morphological, textural and chemical characterization, including nitrogen adsorption-desorption isotherms, Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Boehm titration method and the pH of the point of zero charge (pHPZC).Then they were used as an adsorbent for the removal of COD from wastewater collected from Fez area. Adsorption equilibrium and kinetic data were determined and fitted to several adsorption isotherms and kinetics models, respectively. The results showed that the Langmuir isotherm fitted well the equilibrium data of COD on JSAC adsorbent; whereas, the kinetic data were best fitted by the pseudo-second-order model. This adsorbent showed the highest removal efficiency for COD (72%) and the grey colour of the wastewater (83%) for an optimum dose of 0.5 gJSAC. L-1. Results from the study showed that JSAC activated carbon could be utilized as an effective and less expensive adsorbent for the removal of COD in wastewater.
Cystic teratoma also called dermoid cyst, are congenital benign germinal tumors most commonly found in the ovaries and testes. Pancreatic localization is the least common site of presentation, which make its preoperative diagnosis even more challenging. Herein, we report the case of an 8-year-old girl who presented with abdominal pain localized in the epigastrum. The CT scan showed a well-defined heterogenous cystic mass in the head of the pancreas. At surgery, the entire mass was excised. The diagnosis of a dermoid cyst was then confirmed macroscopically and by histopathology. The main goal of our case report is to show the rarity of this entity and to make a quick review of the literature.
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