High‐color‐purity blue and green organic light‐emitting diodes (OLEDs) have been resolved thanks to the development of B/N‐based polycyclic multiple resonance (MR) emitters. However, due to the derivatization limit of B/N polycyclic structures, the design of red MR emitters remains challenging. Herein, a series of novel red MR emitters is reported by para‐positioning N–π–N, O–π–O, B–π–B pairs onto a benzene ring to construct an MR central core. These emitters can be facilely and modularly synthesized, allowing for easy fine‐tuning of emission spectra by peripheral groups. Moreover, these red MR emitters display excellent photophysical properties such as near‐unity photoluminescence quantum yield (PLQY), fast radiative decay rate (kr) up to 7.4 × 107 s−1, and most importantly, narrowband emission with full‐width at half‐maximum (FWHM) of 32 nm. Incorporating these MR emitters, pure red OLEDs sensitized by phosphor realize state‐of‐the‐art device performances with external quantum efficiency (EQE) exceeding 36%, ultralow efficiency roll‐off (EQE remains as high as 25.1% at the brightness of 50 000 cd m−2), ultrahigh brightness over 130 000 cd m−2, together with good device lifetime.
Blue thermally activated delayed fluorescence (TADF) emitters that can simultaneously achieve narrowband emission and high efficiency in nondoped organic light-emitting diodes (OLEDs) remain a big challenge. Herein, we successfully design...
Non-doped organic light-emitting diodes (OLEDs) are particularly appealing due to the merit of the extremely simple device structure. However, the performance of non-doped OLEDs is usually far inferior than that of doped devices, mainly due to the lack of desirable emitters. An ideal emitter for non-doped OLEDs should not merely be highly emissive in the host matrix but also be capable of delivering excellent properties in its condensed state. Herein, through molecular engineering, an "axial and equatorial carbazolyl extension" approach to manipulate the molecular packing behavior is developed, and thus, the emitter is awarded with superior properties in its neat film. Based on this approach, through simply modifying the conventional acridine donor in a thermally activated delayed fluorescence (TADF) emitter with carbazole moieties in the way of hyper-conjugation, two new TADF emitters with the molecular skeleton being extended both horizontally and vertically by carbazole moieties are constructed. The resulted TADF emitters reveal superb properties with simultaneous excellent thermal and morphological stabilities, photophysical behaviors, and charge transporting ability in their neat film. Owing to the merits of these synergistic superior properties, highly efficient non-doped green emissive OLED with the state-of-the-art external quantum efficiency of nearly 30% is realized.
Wearable
heaters have garnered significant attention from academia
and industry for their great potential in thermotherapy. Silver nanowire
(AgNW) is a promising conductive material for flexible and stretchable
electrodes. Here, a resistive, biaxially stretchable heater based
on AgNW composite is reported for the first time, where a AgNW percolation
network is encased in a thin polyimide (PI) film and integrated with
a highly stretchable textile. AgNW/PI is patterned with a 2D Kirigami
structure, which enables constant resistance under a large tensile
strain (up to uniaxial 100% strain and 50% biaxial strain). The heater
can achieve a high temperature of ∼140 °C with a low current
of 0.125 A, fast heating and cooling rates of ∼16.5 and ∼14.1
°C s–1, respectively, and stable performance
over 400 heating cycles. A feedback control system is developed to
provide constant heating temperature under a temperature change of
the surrounding environment. Demonstrated applications in applying
thermotherapy at the curvilinear surface of the knee using the stretchable
heater illustrate its promising potential for wearable applications.
Objective We propose a method for recognizing driver distraction in real time using a wrist-worn inertial measurement unit (IMU). Background Distracted driving results in thousands of fatal vehicle accidents every year. Recognizing distraction using body-worn sensors may help mitigate driver distraction and consequently improve road safety. Methods Twenty participants performed common behaviors associated with distracted driving while operating a driving simulator. Acceleration data collected from an IMU secured to each driver’s right wrist were used to detect potential manual distractions based on 2-s long streaming data. Three deep neural network-based classifiers were compared for their ability to recognize the type of distractive behavior using F1-scores, a measure of accuracy considering both recall and precision. Results The results indicated that a convolutional long short-term memory (ConvLSTM) deep neural network outperformed a convolutional neural network (CNN) and recursive neural network with long short-term memory (LSTM) for recognizing distracted driving behaviors. The within-participant F1-scores for the ConvLSTM, CNN, and LSTM were 0.87, 0.82, and 0.82, respectively. The between-participant F1-scores for the ConvLSTM, CNN, and LSTM were 0.87, 0.76, and 0.85, respectively. Conclusion The results of this pilot study indicate that the proposed driving distraction mitigation system that uses a wrist-worn IMU and ConvLSTM deep neural network classifier may have potential for improving transportation safety.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.