Electroluminescence has been studied in silicon light-emitting diodes containing oxygen precipitates at temperatures of 40-300 K. Oxygen ion implantation and multistage anneals are used for fabrication of the diodes. Over all temperature range, spectra are well approximated by one Lorentz and four Gaussian curves. Lines of dislocation-related luminescence D1-D4 (the D1 line is described by Lorentz curve) and oxygen precipitates (OPs) are present in the spectra. At temperature variation, peak positions of the D1, OP and D2 lines coincide with temperature dependence of the forbidden gap width reduced by values of 356, 330 and 303 meV respectively. Build and quenching areas are observed on temperature dependences of the electroluminescence intensities of the D1, OP and D2 lines, the activation energies of the processes are determined, and reasons of their appearance are discussed.
Silicon light-emitting diodes with dislocation-related
electroluminescence have been studied at room temperature. For
the fabrication of the light-emitting diode structures, a well-known
method for the formation of dislocation-related luminescence
centers during anneals of silicon with a high oxygen concentration
in a flow of argon was modified by introducing a preliminary
O+- ion implantation and carrying out a final anneal in a chlorine-containing
atmosphere. In the electroluminescence spectra, the
D1 dislocation-related luminescence line dominates at currents
less than 150 mA and the near-band-edge luminescence line starts
to dominate with increasing current. The electroluminescence
excitation efficiency for the D1 center is 3.3 · 10-20 cm2 · s at room
temperature.
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